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Information on EC 1.14.13.75 - vinorine hydroxylase

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The expected taxonomic range for this enzyme is: Rauvolfia serpentina

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1.14.13.75

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vinorine hydroxylase

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vinorine + NADPH + H+ + O2 = vomilenine + NADP+ + H2O

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oxidation

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redox reaction

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reduction

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ajmaline and sarpagine biosynthesis

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Biosynthesis of secondary metabolites

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Indole alkaloid biosynthesis

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vinorine,NADPH:oxygen oxidoreductase (21alpha-hydroxylating)

A heme-thiolate protein (P-450). Forms a stage in the biosynthesis of the indole alkaloid ajmaline.

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162875-03-8

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Rauvolfia serpentina

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Manually annotated by BRENDA team

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vinorine + NADPH + H+ + O2

vomilenine + NADP+ + H2O

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vinorine + NADPH + H+ + O2

vomilenine + NADP+ + H2O

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Rauvolfia serpentina

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enzyme is involved in the biosynthesis of the alkaloid ajmaline

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NADPH

Rauvolfia serpentina

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strictly dependent on

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CO

Rauvolfia serpentina

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cytochrome c

Rauvolfia serpentina

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ketoconazole

Rauvolfia serpentina

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3

NADPH

Rauvolfia serpentina

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26

vinorine

Rauvolfia serpentina

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8.3

Rauvolfia serpentina

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40

Rauvolfia serpentina

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-28°C, 20% sucrose, no loss of activity

Rauvolfia serpentina

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Show References (1 entry)

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NCBI: PubMed, Protein, Nucleotide, Structure, Genome, OMIM

IUBMB Enzyme Nomenclature

PROSITE Database of protein families and domains

Protein Mutant Database

InterPro (database of protein families, domains and functional sites)