Information on EC 1.1.1.257 - 4-(hydroxymethyl)benzenesulfonate dehydrogenase

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The expected taxonomic range for this enzyme is: Comamonas testosteroni

EC NUMBER
COMMENTARY
1.1.1.257
-
RECOMMENDED NAME
GeneOntology No.
4-(hydroxymethyl)benzenesulfonate dehydrogenase
REACTION
REACTION DIAGRAM
COMMENTARY
ORGANISM
UNIPROT ACCESSION NO.
LITERATURE
4-(hydroxymethyl)benzenesulfonate + NAD+ = 4-formylbenzenesulfonate + NADH + H+
show the reaction diagram
Involved in the toluene-4-sulfonate degradation pathway; involved in the toluene-4-sulfonate degradation pathway in Comamonas testeroni
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-
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REACTION TYPE
ORGANISM
UNIPROT ACCESSION NO.
COMMENTARY
LITERATURE
oxidation
-
-
-
-
redox reaction
-
-
-
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reduction
-
-
-
-
PATHWAY
KEGG Link
MetaCyc Link
4-toluenesulfonate degradation I
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Microbial metabolism in diverse environments
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Toluene degradation
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SYSTEMATIC NAME
IUBMB Comments
4-(hydroxymethyl)benzenesulfonate:NAD+ oxidoreductase
Involved in the toluene-4-sulfonate degradation pathway in Comamonas testosteroni.
SYNONYMS
ORGANISM
UNIPROT ACCESSION NO.
COMMENTARY
LITERATURE
sulfobenzyl alcohol dehydrogenase
-
-
sulfobenzyl alcohol dehydrogenase
Comamonas testosteroni T-2
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;
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CAS REGISTRY NUMBER
COMMENTARY
167973-64-0
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ORGANISM
COMMENTARY
LITERATURE
SEQUENCE CODE
SEQUENCE DB
SOURCE
strain PSB-4: loss of reductase component to utilize p-toluenesulfonate to sulfobenzoate , strain TER-1: not able to utilize p-tolunenesulfonate and sulfobenzoate due to deletion of genetic material; strain T-2
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-
Manually annotated by BRENDA team
strain T-2, within a cluster of a four-gene operon, that defines a regulatory unit RI, that is involved in toluenesulfonate degradation
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-
Manually annotated by BRENDA team
Comamonas testosteroni T-2
strain T-2
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-
Manually annotated by BRENDA team
Comamonas testosteroni T-2
strain T-2, within a cluster of a four-gene operon, that defines a regulatory unit RI, that is involved in toluenesulfonate degradation
-
-
Manually annotated by BRENDA team
Comamonas testosteroni TER-1:
strain PSB-4: loss of reductase component to utilize p-toluenesulfonate to sulfobenzoate , strain TER-1: not able to utilize p-tolunenesulfonate and sulfobenzoate due to deletion of genetic material
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-
Manually annotated by BRENDA team
SUBSTRATE
PRODUCT                      
REACTION DIAGRAM
ORGANISM
UNIPROT ACCESSION NO.
COMMENTARY
(Substrate)
LITERATURE
(Substrate)
COMMENTARY
(Product)
LITERATURE
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
4-(hydroxymethyl)benzenesulfonate + NAD+
4-formylbenezenesulfonate + NADH
show the reaction diagram
-
part of a specific transport system that mediates uptake of toluenesulfonat/toluenecarboxylate
-
r
4-(hydroxymethyl)benzenesulfonate + NAD+
4-formylbenezenesulfonate + NADH
show the reaction diagram
-
part of a specific transport system that mediates uptake of toluenesulfonat/toluenecarboxylate
-
r
4-(hydroxymethyl)benzenesulfonate + NAD+
4-formylbenezenesulfonate + NADH
show the reaction diagram
-
part of a specific transport system that mediates uptake of toluenesulfonat/toluenecarboxylate
-
r
4-(hydroxymethyl)benzenesulfonate + NAD+
4-formylbenezenesulfonate + NADH
show the reaction diagram
Comamonas testosteroni T-2
-
part of a specific transport system that mediates uptake of toluenesulfonat/toluenecarboxylate
-
r
4-carboxybenzaldehyde + NADH
4-carboxybenzyl alcohol + NAD+
show the reaction diagram
-
part of a specific transport system that mediates uptake of toluenesulfonat/toluenecarboxylate pathway of degradation
-
r
4-carboxybenzaldehyde + NADH
4-carboxybenzyl alcohol + NAD+
show the reaction diagram
-
involved in the degradation of toluenesulfonate and toluenecarboxylate
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r
4-carboxybenzaldehyde + NADH
4-carboxybenzyl alcohol + NAD+
show the reaction diagram
-
involved in the degradation of toluenesulfonate and toluenecarboxylate
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r
4-carboxybenzaldehyde + NADH
4-carboxybenzyl alcohol + NAD+
show the reaction diagram
-
involved in the degradation of toluenesulfonate and toluenecarboxylate
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r
4-carboxybenzaldehyde + NADH
4-carboxybenzyl alcohol + NAD+
show the reaction diagram
Comamonas testosteroni PSB-4, Comamonas testosteroni T-2
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involved in the degradation of toluenesulfonate and toluenecarboxylate
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r
4-carboxybenzaldehyde + NADH
4-carboxybenzyl alcohol + NAD+
show the reaction diagram
Comamonas testosteroni T-2
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part of a specific transport system that mediates uptake of toluenesulfonat/toluenecarboxylate pathway of degradation
-
r
4-carboxybenzaldehyde + NADH
4-carboxybenzyl alcohol + NAD+
show the reaction diagram
Comamonas testosteroni T-2
-
involved in the degradation of toluenesulfonate and toluenecarboxylate
-
r
4-carboxybenzaldehyde + NADH
4-carboxybenzyl alcohol + NAD+
show the reaction diagram
Comamonas testosteroni TER-1:
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involved in the degradation of toluenesulfonate and toluenecarboxylate
-
r
COFACTOR
ORGANISM
UNIPROT ACCESSION NO.
COMMENTARY
LITERATURE
IMAGE
METALS and IONS
ORGANISM
UNIPROT ACCESSION NO.
COMMENTARY
LITERATURE
Fe2+
-
2Fe-2S-Rieske center
SOURCE TISSUE
ORGANISM
UNIPROT ACCESSION NO.
COMMENTARY
LITERATURE
SOURCE
Comamonas testosteroni PSB-4, Comamonas testosteroni T-2, Comamonas testosteroni TER-1:
-
-
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Manually annotated by BRENDA team
LOCALIZATION
ORGANISM
UNIPROT ACCESSION NO.
COMMENTARY
GeneOntology No.
LITERATURE
SOURCE
MOLECULAR WEIGHT
MOLECULAR WEIGHT MAXIMUM
ORGANISM
UNIPROT ACCESSION NO.
COMMENTARY
LITERATURE
102000
-
-
gel filtration
SUBUNITS
ORGANISM
UNIPROT ACCESSION NO.
COMMENTARY
LITERATURE
dimer
-
2 * 51000, SDS-PAGE
dimer
Comamonas testosteroni T-2
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2 * 51000, SDS-PAGE
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POSTTRANSLATIONAL MODIFICATION
ORGANISM
UNIPROT ACCESSION NO.
COMMENTARY
LITERATURE
additional information
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iron-sulfur flavoprotein
Purification/COMMENTARY
ORGANISM
UNIPROT ACCESSION NO.
LITERATURE
to homogeneity, chromatography techniques
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