6.3.2.47: dapdiamide synthase

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For detailed information about dapdiamide synthase, go to the full flat file.

Reaction

3-({[(2R,3R)-3-carbamoyloxiran-2-yl]carbonyl}amino)-L-alanine

3-({[(2R,3R)-3-carbamoyloxiran-2-yl]carbonyl}amino)-L-alanyl-L-valine

Synonyms

DdaF, {[(2E)-4-amino-4-oxobut-2-enoyl]amino}-L-alanine:L-valine ligase (ADP-forming)

ECTree

6 Ligases

6.3 Forming carbon-nitrogen bonds

6.3.2 Acid—amino-acid ligases (peptide synthases)

6.3.2.47 dapdiamide synthase

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Results	in table
27	AA Sequence
1	Cloned(Commentary)
1	General Information
1	Inhibitors
2	kcat/KM [mM/s]
5	KM Value [mM]
2	Organism
6	Pathway
4	Reaction
2	Reference
6	Substrates and Products (Substrate)
2	Synonyms
1	Systematic Name
2	Turnover Number [1/s]

Reaction

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Reaction on EC 6.3.2.47 - dapdiamide synthase

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ATP + 3-({[(2R,3R)-3-carbamoyloxiran-2-yl]carbonyl}amino)-L-alanine + L-valine = ADP + phosphate + 3-({[(2R,3R)-3-carbamoyloxiran-2-yl]carbonyl}amino)-L-alanyl-L-valine

(4)

ATP + 3-{[(2E)-4-amino-4-oxobut-2-enoyl]amino}-L-alanine + L-isoleucine = ADP + phosphate + 3-{[(2E)-4-amino-4-oxobut-2-enoyl]amino}-L-alanyl-L-isoleucine

(2)

ATP + 3-{[(2E)-4-amino-4-oxobut-2-enoyl]amino}-L-alanine + L-leucine = ADP + phosphate + 3-{[(2E)-4-amino-4-oxobut-2-enoyl]amino}-L-alanyl-L-leucine

(3)

ATP + 3-{[(2E)-4-amino-4-oxobut-2-enoyl]amino}-L-alanine + L-valine = ADP + phosphate + 3-{[(2E)-4-amino-4-oxobut-2-enoyl]amino}-L-alanyl-L-valine

(1)