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6.3.1.7: 4-methyleneglutamate-ammonia ligase

This is an abbreviated version!
For detailed information about 4-methyleneglutamate-ammonia ligase, go to the full flat file.

Reaction

ATP
+
4-methylene-L-glutamate
+
NH3
=
AMP
+
diphosphate
+
4-methylene-L-glutamine

Synonyms

4-Methyleneglutamine synthetase, 4-Methylenenglutamate:ammonia ligase (AMP-forming), Synthetase, methyleneglutamine

ECTree

     6 Ligases
         6.3 Forming carbon-nitrogen bonds
             6.3.1 Acid—ammonia (or amine) ligases (amide synthases)
                6.3.1.7 4-methyleneglutamate-ammonia ligase

Substrates Products

Substrates Products on EC 6.3.1.7 - 4-methyleneglutamate-ammonia ligase

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SUBSTRATE
PRODUCT                       
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
ATP + 4-methylene-L-glutamate + glutamine
AMP + diphosphate + glutamate + 4-methylene-L-glutamine
show the reaction diagram
-
about 20% as effective as NH4+
-
-
?
ATP + 4-methylene-L-glutamate + hydroxylamine
AMP + diphosphate + 4-methylene-L-glutamylhydroxamate
show the reaction diagram
-
70% as effective as NH4+
-
-
?
ATP + 4-methylene-L-glutamate + NH3
?
show the reaction diagram
-
enzyme is responsible for the rapid synthesis of 4-methyleneglutamine which occurs in germinating peanuts
-
-
?
ATP + 4-methylene-L-glutamate + NH4+
AMP + diphosphate + 4-methylene-L-glutamine
show the reaction diagram
additional information
?
-
-
no amide/hydroxylamine exchange
-
-
?