5.5.1.8: (+)-bornyl diphosphate synthase
This is an abbreviated version!
For detailed information about (+)-bornyl diphosphate synthase, go to the full flat file.
Word Map on EC 5.5.1.8
Reaction
Synonyms
(+)-bornyl diphosphate synthase, (+)-Bornylpyrophosphate cyclase, (+)-BPP cyclase, (-)-BPP cyclase, (di)terpene synthase, bornyl diphosphate synthase, bornyl pyrophosphate synthase, bornyl pyrophosphate synthetase, BPPS, BPS, Geranyl pyrophosphate:(+)-bornyl pyrophosphate cyclase, Geranyl pyrophosphate:(-)-bornyl pyrophosphate cyclase, geranyl-diphosphate cyclase, Synthetase, bornyl pyrophosphate, TPS3
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5.5.1.8 (+)-bornyl diphosphate synthaseAdvanced search results
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Natural Substrates Products on EC 5.5.1.8 - (+)-bornyl diphosphate synthase
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NATURAL SUBSTRATE 
NATURAL PRODUCT
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate)
(Substrate)
LITERATURE
(Substrate)
(Substrate)
COMMENTARY
(Product)
(Product)
LITERATURE
(Product)
(Product)
REVERSIBILITY
r=reversible
ir=irreversible
?=not specified
r=reversible
ir=irreversible
?=not specified
Geranyl diphosphate
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formation of bornyl diphosphate is the rate-limiting step in camphor biosynthesis even in immature leaf tissue
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additional information
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(di)terpene synthases seem to mediate specific reaction outcomes, at least in part, by providing electrostatic effects to counteract those exerted by the diphosphate co-product. Role for the diphosphate anion co-product in the reaction catalyzed by monoterpene cyclases, such as bornyl diphosphate synthase
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geranyl diphosphate
(+)-bornyl diphosphate
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the enzyme is involved in monoterpenoid cyclase catalysis, mechanism of this coupled isomerization-cyclization reaction, modeling, overview
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