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5.5.1.24: tocopherol cyclase

This is an abbreviated version!
For detailed information about tocopherol cyclase, go to the full flat file.

Word Map on EC 5.5.1.24

Reaction

delta-tocopherol
=
2-methyl-6-phytylbenzene-1,4-diol

Synonyms

2,3-dimethyl-5-phytyl-1,4-hydroquinone cyclase, DMPQ cyclase, slr1737, SXD1, TC/VTE1, VTE1

ECTree

     5 Isomerases
         5.5 Intramolecular lyases
             5.5.1 Intramolecular lyases (only sub-subclass identified to date)
                5.5.1.24 tocopherol cyclase

Substrates Products

Substrates Products on EC 5.5.1.24 - tocopherol cyclase

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SUBSTRATE
PRODUCT                       
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
2,3,5-trimethyl-6-[(2E,7S,11S)-3,7,11,15-tetramethylhexadec-2-en-1-yl]benzene-1,4-diol
alpha-tocopherol
show the reaction diagram
-
-
-
-
?
2,3-dimethyl-5-phytyl-1,4-benzoquinone
gamma-tocopherol
show the reaction diagram
2,3-dimethyl-5-[(2E,6E)-3,7,11-trimethyldodeca-2,6,10-trien-1-yl]benzene-1,4-diol
(2R)-2-[(3E)-4,8-dimethylnona-3,7-dien-1-yl]-2,7,8-trimethyl-3,4-dihydro-2H-chromen-6-ol
show the reaction diagram
-
-
-
-
?
2,3-dimethyl-5-[(2E,6E,10E)-3,7,11,15-tetramethylhexadeca-2,6,10,14-tetraen-1-yl]benzene-1,4-diol
(2R)-2,7,8-trimethyl-2-[(3E,7E)-4,8,12-trimethyltrideca-3,7,11-trien-1-yl]-3,4-dihydro-2H-chromen-6-ol
show the reaction diagram
-
-
-
-
?
2,3-dimethyl-6-phytylbenzene-1,4-diol
gamma-tocopherol
show the reaction diagram
2,5-dimethyl-3-[(2E,7S,11S)-3,7,11,15-tetramethylhexadec-2-en-1-yl]benzene-1,4-diol
beta-tocopherol
show the reaction diagram
-
-
-
-
?
2-methyl-6-phytyl-1,4-benzoquinone
delta-tocopherol
show the reaction diagram
2-methyl-6-phytylbenzene-1,4-diol
delta-tocopherol
show the reaction diagram
2-methyl-6-phytylplastoquinone
delta-tocopherol
show the reaction diagram
-
-
-
-
?
2-methyl-6-[(2E,7S,11S)-3,7,11,15-tetramethylhexadec-2-en-1-yl]benzene-1,4-diol
delta-tocopherol
show the reaction diagram
-
-
-
-
?
2-[(2E,7S,11S)-3,7,11,15-tetramethylhexadec-2-en-1-yl]benzene-1,4-diol
tocol
show the reaction diagram
-
-
-
-
?
3,5-dimethyl-2-[(2E,7S,11S)-3,7,11,15-tetramethylhexadec-2-en-1-yl]benzene-1,4-diol
zeta-tocopherol
show the reaction diagram
-
-
-
-
?
6-geranylgeranyl-2,3-dimethylbenzene-1,4-diol
gamma-tocotrienol
show the reaction diagram
-
-
-
?
delta-tocopherol
2-methyl-6-phytylbenzene-1,4-diol
show the reaction diagram
gamma-tocopherol
2,3-dimethyl-6-phytylbenzene-1,4-diol
show the reaction diagram
plastoquinol
plastoquinol
show the reaction diagram
-
-
-
-
?
plastoquinol-9
plastochromanol-8
show the reaction diagram