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5.4.99.14: 4-carboxymethyl-4-methylbutenolide mutase

This is an abbreviated version!
For detailed information about 4-carboxymethyl-4-methylbutenolide mutase, go to the full flat file.

Reaction

4-carboxymethyl-4-methylbut-2-en-1,4-olide
=
4-Carboxymethyl-3-methylbut-2-en-1,4-olide

Synonyms

4-Methyl-3-enelactone methyl isomerase, 4-Methylmuconolactone methylisomerase, Isomerase, 4-methyl-2-enelactone, methymuconolactone isomerase, MLMI, MmlJ

ECTree

     5 Isomerases
         5.4 Intramolecular transferases
             5.4.99 Transferring other groups
                5.4.99.14 4-carboxymethyl-4-methylbutenolide mutase

Substrates Products

Substrates Products on EC 5.4.99.14 - 4-carboxymethyl-4-methylbutenolide mutase

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SUBSTRATE
PRODUCT                       
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
(4R,5R)-5-chloro-3-methylmuconolactone
trans-3-methyldienelactone
show the reaction diagram
(4S)-4-methylmuconolactone
(4S)-3-methylmuconolactone
show the reaction diagram
-
-
-
?
(4S,5S)-5-chloro-3-methylmuconolactone
trans-3-methyldienelactone
show the reaction diagram
1-methylbis-lactone
?
show the reaction diagram
-
-
-
?
1-Methylbislactone
4-Carboxymethyl-3-methylbut-2-en-1,4-olide
show the reaction diagram
3-methylmuconolactone
4-methyl-3-oxoadipate enollactone
show the reaction diagram
-
-
-
-
?
4-Carboxymethyl-4-methylbut-2-en-1,4-olide
4-Carboxymethyl-3-methylbut-2-en-1,4-olide
show the reaction diagram
4-Carboxymethyl-4-methylbut-2-en-1,4-olide
?
show the reaction diagram
-
enzyme of the modified 3-oxoadipate pathway in the Gram-negative bacterium Alcaligenes eutrophus JMP 134
-
-
?
4-methyl-muconolactone
3-methyl-muconolactone
show the reaction diagram
additional information
?
-