5.4.4.6: 9,12-octadecadienoate 8-hydroperoxide 8S-isomerase
This is an abbreviated version!
For detailed information about 9,12-octadecadienoate 8-hydroperoxide 8S-isomerase, go to the full flat file.
Reaction
Synonyms
7,8-diol synthase, 7,8-LDS, 7,8-linoleate diol synthase, EC 1.13.11.44
ECTree
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Inhibitors
Inhibitors on EC 5.4.4.6 - 9,12-octadecadienoate 8-hydroperoxide 8S-isomerase
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catalysis declines due to suicide inactivation; catalysis declines due to suicide inactivation. Following column chromatography, e.g. ion exchange or zinc-affinity chromatography, hydroperoxide isomerase activity is often decreased and sometimes even undetectable by TLC, whereas 8-dioxygenase activity is always present. However, storage of the enzyme for a few days on ice often restores the hydroperoxide isomerase and appeares to increase the LDS activity as well
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additional information
catalysis declines due to suicide inactivation; catalysis declines due to suicide inactivation. Following column chromatography, e.g. ion exchange or zinc-affinity chromatography, hydroperoxide isomerase activity is often decreased and sometimes even undetectable by TLC, whereas 8-dioxygenase activity is always present. However, storage of the enzyme for a few days on ice often restores the hydroperoxide isomerase and appeares to increase the LDS activity as well
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