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5.4.3.6: tyrosine 2,3-aminomutase

This is an abbreviated version!
For detailed information about tyrosine 2,3-aminomutase, go to the full flat file.

Word Map on EC 5.4.3.6

Reaction

L-tyrosine
=
3-amino-3-(4-hydroxyphenyl)propanoate

Synonyms

3,5-dihydro-5-methylidene-4H-imidazol-4-one-dependent aminomutase, 3,5-dihydro-5-methylidine-4H-imidazol-4-one-dependent tyrosine aminomutase, Aminomutase, tyrosine 2,3-, CmdF, MfTAM, MIO-dependent aminomutase, MIO-dependent tyrosine aminomutase, More, MxTAM, OsTAM, SgcC4, TAM, Tam1, Tyrosine alpha,beta-amino mutase, Tyrosine alpha,beta-mutase, tyrosine aminomutase

ECTree

     5 Isomerases
         5.4 Intramolecular transferases
             5.4.3 Transferring amino groups
                5.4.3.6 tyrosine 2,3-aminomutase

Substrates Products

Substrates Products on EC 5.4.3.6 - tyrosine 2,3-aminomutase

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SUBSTRATE
PRODUCT                       
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
(3S)-amino-3-(4-hydroxyphenyl)propanoate
(3R)-amino-3-(4-hydroxyphenyl)propanoate
show the reaction diagram
-
beta-tyrosine racemase activity
-
r
4-bromo-L-phenylalanine
4-bromo-L-beta-phenylalanine
show the reaction diagram
-
-
-
-
?
4-chloro-L-phenylalanine
4-chloro-L-beta-phenylalanine
show the reaction diagram
-
-
-
-
?
4-fluoro-L-phenylalanine
4-fluoro-L-beta-phenylalanine
show the reaction diagram
-
-
-
-
?
L-3,4-dihydroxyphenylalanine
3-amino-3-(3,4-dihydroxyphenyl)propanoate
show the reaction diagram
-
-
-
?
L-3-chlorotyrosine
3-amino-3-(3-chloro-4-hydroxyphenyl)propanoate
show the reaction diagram
-
-
-
?
L-phenylalanine
L-beta-phenylalanine
show the reaction diagram
-
3% relative to the activity with L-tyrosine of wild-type enzyme
-
-
?
L-Tyr
3-Amino-3-(4-hydroxyphenyl)propanoate
show the reaction diagram
-
-
i.e. beta-Tyr
?
L-Tyr
?
show the reaction diagram
-
formation of beta-Tyr which is the N-terminal amino acid of the antibiotic edeine
-
-
?
L-tyrosine
(4-hydroxyphenyl)prop-2-enoate + NH3
show the reaction diagram
-
ammonia lyase activity of tyrosine aminomutase
-
?
L-tyrosine
(R)-beta-tyrosine
show the reaction diagram
L-tyrosine
(S)-beta-tyrosine
show the reaction diagram
L-tyrosine
3-amino-3-(4-hydroxyphenyl)propanoate
show the reaction diagram
L-tyrosine
4-hydroxycinnamic acid + NH3
show the reaction diagram
-
-
-
?
[3-deutero]-(2S,3R)-alpha-tyrosine
[3-deutero]-(2S,3S)-4'-O,2-N-di((S)-2-methylbutanoic acid)-alpha-tyrosine methyl ester + [3-deutero]-(2S,3R)-4'-O,2-N-di((S)-2-methylbutanoic acid)-alpha-tyrosine methyl ester
show the reaction diagram
-
-
-
-
?
[3-deutero]-(2S,3S)-alpha-tyrosine
[3-deutero]-(2S,3S)-4'-O,2-N-di((S)-2-methylbutanoic acid)-alpha-tyrosine methyl ester + ([3-deutero]-(2S,3R)-4'-O,2-N-di((S)-2-methylbutanoic acid)-alpha-tyrosine methyl ester
show the reaction diagram
-
-
-
-
?
additional information
?
-