5.3.2.6: 2-hydroxymuconate tautomerase
This is an abbreviated version!
For detailed information about 2-hydroxymuconate tautomerase, go to the full flat file.
Word Map on EC 5.3.2.6
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5.3.2.6
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tautomerization
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michael-type
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trans-3-chloroacrylic
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5-carboxymethyl-2-hydroxymuconate
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2-oxo-3-pentynoate
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stivers
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dienolic
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heterohexamer
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2-hydroxy-2,4-pentadienoate
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3-bromopyruvate
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beta-alpha-beta
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whitman
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proline-based
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3-chloroacrylic
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cis-caad
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meta-fission
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cis-3-chloroacrylic
- 5.3.2.6
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tautomerization
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michael-type
-
trans-3-chloroacrylic
- 5-carboxymethyl-2-hydroxymuconate
- 2-oxo-3-pentynoate
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stivers
-
dienolic
-
heterohexamer
- 2-hydroxy-2,4-pentadienoate
- 3-bromopyruvate
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beta-alpha-beta
-
whitman
-
proline-based
-
3-chloroacrylic
- cis-caad
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meta-fission
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cis-3-chloroacrylic
Reaction
Synonyms
4-OT, 4-oxalocrotonate tautomerase, 4-oxalocrotonate tautomerase I, 4-oxalocrotonate tautomerase II, 4OT, AfDmpI, D-4-oxalocrotonate tautomerase, HpDmpI, L-4-oxalocrotonate tautomerase, OCA, PRAC, SAR1376, TomN, xylH, YwhB
ECTree
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Inhibitors
Inhibitors on EC 5.3.2.6 - 2-hydroxymuconate tautomerase
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(2E)-fluoromuconate
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a dicarboxylate competitive inhibitor, shows substoichiometric binding to 3 +/- 1 sites per hexamer
3-Bromopyruvate
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a active-site-directed irreversible inhibitor, modification of three active sites per hexamer abolishes essentially all activity of the hexamer, pH dependence of inactivation
additional information
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although 4-OT exhibits no structural asymmetry either by X-ray or by NMR, inactivation by two affinity labels shows half-site stoichiometry
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