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5.3.2.4: TDP-4-oxo-6-deoxy-alpha-D-glucose-3,4-oxoisomerase (dTDP-3-dehydro-6-deoxy-alpha-D-glucopyranose-forming)

This is an abbreviated version!
For detailed information about TDP-4-oxo-6-deoxy-alpha-D-glucose-3,4-oxoisomerase (dTDP-3-dehydro-6-deoxy-alpha-D-glucopyranose-forming), go to the full flat file.

Reaction

dTDP-4-dehydro-6-deoxy-alpha-D-glucopyranose
=
dTDP-3-dehydro-6-deoxy-alpha-D-glucopyranose

Synonyms

TDP-4-keto-6-deoxy-D-glucose-3,4-ketoisomerase, Tyl1a

ECTree

     5 Isomerases
         5.3 Intramolecular oxidoreductases
             5.3.2 Interconverting keto- and enol-groups
                5.3.2.4 TDP-4-oxo-6-deoxy-alpha-D-glucose-3,4-oxoisomerase (dTDP-3-dehydro-6-deoxy-alpha-D-glucopyranose-forming)

Substrates Products

Substrates Products on EC 5.3.2.4 - TDP-4-oxo-6-deoxy-alpha-D-glucose-3,4-oxoisomerase (dTDP-3-dehydro-6-deoxy-alpha-D-glucopyranose-forming)

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SUBSTRATE
PRODUCT                       
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
CDP-4-dehydro-6-deoxy-alpha-D-glucose
CDP-3-dehydro-6-deoxy-alpha-D-glucose
show the reaction diagram
-
efficiency of conversion is low, requiring a high concentration of enzyme and a long incubation time to achieve significant turnover
-
-
?
dTDP-4-dehydro-2,6-dideoxy-alpha-D-glucose
dTDP-3-dehydro-2,6-dideoxy-alpha-D-glucose
show the reaction diagram
-
efficiency is comparable to that with dTDP-6-deoxy-D-xylo-hexopyranos-4-ulose
-
-
?
dTDP-4-dehydro-6-deoxy-alpha-D-glucopyranose
dTDP-3-dehydro-6-deoxy-alpha-D-glucopyranose
show the reaction diagram
-
-
-
-
?
dTDP-4-dehydro-6-deoxy-alpha-D-glucose
dTDP-3-dehydro-6-deoxy-alpha-D-glucose
show the reaction diagram
-
the enzyme is involved in the D-mycaminose biosynthetic pathway
-
-
?