5.3.2.3: TDP-4-oxo-6-deoxy-alpha-D-glucose-3,4-oxoisomerase (dTDP-3-dehydro-6-deoxy-alpha-D-galactopyranose-forming)

This is an abbreviated version!
For detailed information about TDP-4-oxo-6-deoxy-alpha-D-glucose-3,4-oxoisomerase (dTDP-3-dehydro-6-deoxy-alpha-D-galactopyranose-forming), go to the full flat file.

Reaction

Synonyms

dTDP-6-deoxy-D-xylo-hexos-4-ulose 3,4-ketoisomerase, FdtA, RavIM, TDP-4-keto-6-deoxy-D-glucose-3,4-ketoisomerase

ECTree

     5 Isomerases

         5.3 Intramolecular oxidoreductases

             5.3.2 Interconverting keto- and enol-groups

                5.3.2.3 TDP-4-oxo-6-deoxy-alpha-D-glucose-3,4-oxoisomerase (dTDP-3-dehydro-6-deoxy-alpha-D-galactopyranose-forming)

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Results	in table
201	AA Sequence
1	Application
4	Cloned(Commentary)
2	Crystallization (Commentary)
1	General Stability
5	kcat/KM [mM/s]
5	KM Value [mM]
1	Molecular Weight [Da]
7	Natural Substrates/ Products (Substrates)
8	Organism
6	Pathway
3	pH Optimum
10	Protein Variants
4	Purification (Commentary)
1	Reaction
8	Reference
1	Storage Stability
13	Substrates and Products (Substrate)
3	Subunits
9	Synonyms
1	Systematic Name
4	Temperature Optimum [°C]
5	Turnover Number [1/s]

Natural Substrates Products

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Natural Substrates Products on EC 5.3.2.3 - TDP-4-oxo-6-deoxy-alpha-D-glucose-3,4-oxoisomerase (dTDP-3-dehydro-6-deoxy-alpha-D-galactopyranose-forming)

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NATURAL SUBSTRATE

NATURAL PRODUCT

REACTION DIAGRAM

ORGANISM

UNIPROT

COMMENTARY
(Substrate)

LITERATURE
(Substrate)

COMMENTARY
(Product)

LITERATURE
(Product)

REVERSIBILITY
r=reversible
ir=irreversible
?=not specified

dTDP-4-dehydro-6-deoxy-alpha-D-glucopyranose

?

Streptomyces ravidus

-

-

716410

-

-

?

dTDP-4-dehydro-6-deoxy-alpha-D-glucopyranose

dTDP-3-dehydro-6-deoxy-alpha-D-galactopyranose

6 entries

dTDP-4-dehydro-6-deoxy-alpha-D-glucopyranose

dTDP-3-dehydro-6-deoxy-alpha-D-galactopyranose

Acinetobacter baumannii

-

-

748614

-

-

?

dTDP-4-dehydro-6-deoxy-alpha-D-glucopyranose

dTDP-3-dehydro-6-deoxy-alpha-D-galactopyranose

Acinetobacter baumannii RCH51

-

-

748614

-

-

?

dTDP-4-dehydro-6-deoxy-alpha-D-glucopyranose

dTDP-3-dehydro-6-deoxy-alpha-D-galactopyranose

Aneurinibacillus thermoaerophilus

Q6T1W8

i.e. dTDP-6-deoxy-D-xylo-hexopyranos-4-ulose. The glycan chain of the S-layer protein of Aneurinibacillus thermoaerophilus L420-91T (DSM 10154) consists of D-rhamnose and 3-acetamido-3,6-dideoxy-D-galactose (D-Fucp3NAc). Thymidine diphosphate-activated (D-Fucp3NAc) serves as precursor for the assembly of structural polysaccharides in Gram-positive and Gram-negative organisms. The biosynthesis of dTDP-3-acetamido-3,6-dideoxy-alpha-D-galactose (dTDP-D-Fucp3NAc) involves five enzymes. FdtA is involved in this pathway

715462

i.e. dTDP-6-deoxy-D-xylo-hexopyranos-3-ulose

-

r

dTDP-4-dehydro-6-deoxy-alpha-D-glucopyranose

dTDP-3-dehydro-6-deoxy-alpha-D-galactopyranose

Aneurinibacillus thermoaerophilus

Q6T1W8

the enzyme is involved in the biosynthesis of dTDP-3-acetamido-3,6-dideoxy-alpha-D-galactose. Four moieties of alpha-D-rhamnose and two moities of 3-acetamido-3,6-dideoxy-alpha-D-galactose form the repeating unit of the glycan chain in the S-layer of the bacterium Aneurinibacillus thermoaerophilus

715487

-

-

?

dTDP-4-dehydro-6-deoxy-alpha-D-glucopyranose

dTDP-3-dehydro-6-deoxy-alpha-D-galactopyranose

Aneurinibacillus thermoaerophilus L420-91T

Q6T1W8

the enzyme is involved in the biosynthesis of dTDP-3-acetamido-3,6-dideoxy-alpha-D-galactose. Four moieties of alpha-D-rhamnose and two moities of 3-acetamido-3,6-dideoxy-alpha-D-galactose form the repeating unit of the glycan chain in the S-layer of the bacterium Aneurinibacillus thermoaerophilus

715487

-

-

?

dTDP-4-dehydro-6-deoxy-alpha-D-glucopyranose

dTDP-3-dehydro-6-deoxy-alpha-D-galactopyranose

Aneurinibacillus thermoaerophilus L420-91T, DSM 10154

Q6T1W8

i.e. dTDP-6-deoxy-D-xylo-hexopyranos-4-ulose. The glycan chain of the S-layer protein of Aneurinibacillus thermoaerophilus L420-91T (DSM 10154) consists of D-rhamnose and 3-acetamido-3,6-dideoxy-D-galactose (D-Fucp3NAc). Thymidine diphosphate-activated (D-Fucp3NAc) serves as precursor for the assembly of structural polysaccharides in Gram-positive and Gram-negative organisms. The biosynthesis of dTDP-3-acetamido-3,6-dideoxy-alpha-D-galactose (dTDP-D-Fucp3NAc) involves five enzymes. FdtA is involved in this pathway

715462

i.e. dTDP-6-deoxy-D-xylo-hexopyranos-3-ulose

-

r