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4.2.99.23: tuliposide B-converting enzyme

This is an abbreviated version!
For detailed information about tuliposide B-converting enzyme, go to the full flat file.

Word Map on EC 4.2.99.23

Reaction

6-tuliposide B
=
tulipalin B
+
D-glucose

Synonyms

6-PosB-converting enzyme, ignition enzyme, non-ester-hydrolyzing TCE, Pos-converting enzyme, PosB-converting enzyme, TCE, TCEB, TCEB1, TgTCEB1, tuliposide B converting enzyme, tuliposide B-converting enzyme, tuliposide-converting enzyme

ECTree

     4 Lyases
         4.2 Carbon-oxygen lyases
             4.2.99 Other carbon-oxygen lyases
                4.2.99.23 tuliposide B-converting enzyme

Systematic Name

Systematic Name on EC 4.2.99.23 - tuliposide B-converting enzyme

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SYSTEMATIC NAME
IUBMB Comments
6-tuliposide B D-glucose-lyase (tulipalin B-forming)
The enzyme, characterized from pollen of the plant Tulipa gesneriana (tulip), catalyses the intramolecular transesterification of 6-tuliposide B to form the antibiotic aglycon tulipalin B as a sole product. It does not catalyse the hydrolysis of 6-tuliposide B to form a hydroxy acid. The enzyme has marginal activity with 6-tuliposide A. cf. EC 4.2.99.22, tuliposide A-converting enzyme.