4.2.99.20: 2-succinyl-6-hydroxy-2,4-cyclohexadiene-1-carboxylate synthase

This is an abbreviated version!
For detailed information about 2-succinyl-6-hydroxy-2,4-cyclohexadiene-1-carboxylate synthase, go to the full flat file.

Reaction

Synonyms

(1R,6R)-2-succinyl-6-hydroxy-2,4-cyclohexadiene-1-carboxylate synthase, EC 2.5.1.64, MenH, SHCHC, SHCHC synthase, YfbB

ECTree

     4 Lyases

         4.2 Carbon-oxygen lyases

             4.2.99 Other carbon-oxygen lyases

                4.2.99.20 2-succinyl-6-hydroxy-2,4-cyclohexadiene-1-carboxylate synthase

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Results	in table
6542	AA Sequence
1	CAS Registry Number
3	Cloned(Commentary)
3	Crystallization (Commentary)
1	General Information
24	kcat/KM [mM/s]
29	KM Value [mM]
1	Metals/Ions
1	Molecular Weight [Da]
2	Natural Substrates/ Products (Substrates)
6	Organism
6	Pathway
17	PDB ID
1	pH Optimum
25	Protein Variants
3	Purification (Commentary)
2	Reaction
1	Reaction Type
6	Reference
7	Substrates and Products (Substrate)
2	Subunits
11	Synonyms
1	Systematic Name
1	Temperature Optimum [°C]
24	Turnover Number [1/s]

Natural Substrates Products

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Natural Substrates Products on EC 4.2.99.20 - 2-succinyl-6-hydroxy-2,4-cyclohexadiene-1-carboxylate synthase

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NATURAL SUBSTRATE

NATURAL PRODUCT

REACTION DIAGRAM

ORGANISM

UNIPROT

COMMENTARY
(Substrate)

LITERATURE
(Substrate)

COMMENTARY
(Product)

LITERATURE
(Product)

REVERSIBILITY
r=reversible
ir=irreversible
?=not specified

5-enolpyruvoyl-6-hydroxy-2-succinyl-cyclohex-3-ene-1-carboxylate

(1R,6R)-6-hydroxy-2-succinylcyclohexa-2,4-diene-1-carboxylate + pyruvate

2 entries

5-enolpyruvoyl-6-hydroxy-2-succinyl-cyclohex-3-ene-1-carboxylate

(1R,6R)-6-hydroxy-2-succinylcyclohexa-2,4-diene-1-carboxylate + pyruvate

Escherichia coli

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step in menaquinone biosynthesis

685225

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-

?

5-enolpyruvoyl-6-hydroxy-2-succinyl-cyclohex-3-ene-1-carboxylate

(1R,6R)-6-hydroxy-2-succinylcyclohexa-2,4-diene-1-carboxylate + pyruvate

Escherichia coli K-12

-

the enzyme is involved in biosynthesis of vitamin K2 (manoquinone). Under basic conditions, the product can spontaneously lose pyruvate to form (1R,6R)-6-hydroxy-2-succinylcyclohexa-2,4-diene-1-carboxylate

685086

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-

?