4.2.3.97: (-)-delta-cadinene synthase
This is an abbreviated version!
For detailed information about (-)-delta-cadinene synthase, go to the full flat file.
Reaction
Synonyms
SCreLAV_p0328, sscg_02150
ECTree
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Systematic Name
Systematic Name on EC 4.2.3.97 - (-)-delta-cadinene synthase
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(2E,6E)-farnesyl diphosphate diphosphate-lyase (cyclizing, (-)-delta-cadinene-forming)
The cyclization mechanism involves an intermediate nerolidyl diphosphate leading to a helminthogermacradienyl cation. Following a 1,3-hydride shift of the original 1-pro-S hydrogen of (2E,6E)-farnesyl diphosphate, cyclization and deprotonation gives (-)-delta-cadinene.