4.2.3.97: (-)-delta-cadinene synthase
This is an abbreviated version!
For detailed information about (-)-delta-cadinene synthase, go to the full flat file.
Reaction
Synonyms
SCreLAV_p0328, sscg_02150
ECTree
4.2.3.97 (-)-delta-cadinene synthaseAdvanced search results
results (
results (| Results | in table |
|---|---|
| 3 | AA Sequence |
| 1 | Cloned(Commentary) |
| 2 | KM Value [mM] |
| 2 | Organism |
| 3 | Reaction |
| 2 | Reference |
| 4 | Substrates and Products (Substrate) |
| 4 | Synonyms |
| 1 | Systematic Name |
| 2 | Turnover Number [1/s] |
Substrates Products
Substrates Products on EC 4.2.3.97 - (-)-delta-cadinene synthase
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SUBSTRATE 
PRODUCT
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate)
(Substrate)
LITERATURE
(Substrate)
(Substrate)
COMMENTARY
(Product)
(Product)
LITERATURE
(Product)
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
r=reversible
ir=irreversible
?=not specified
(2E,6E)-farnesyl diphosphate
(-)-delta-cadinene + diphosphate
-
-
-
?
(2E,6E)-farnesyl diphosphate
(-)-delta-cadinene + diphosphate
cyclization mechanism involves the intermediacy of nerolidyl diphosphate leading to a helminthogermacradienyl cation. Following a 1,3-hydride shift of the original H-1si of farnesyl diphosphate, cyclization and deprotonation will give (-)-delta-cadinene
more than 95% of product
-
?
(2E,6E)-farnesyl diphosphate
(-)-delta-cadinene + diphosphate
-
-
-
?
(2E,6E)-farnesyl diphosphate
(-)-delta-cadinene + diphosphate
cyclization mechanism involves the intermediacy of nerolidyl diphosphate leading to a helminthogermacradienyl cation. Following a 1,3-hydride shift of the original H-1si of farnesyl diphosphate, cyclization and deprotonation will give (-)-delta-cadinene
more than 95% of product
-
?
