4.2.3.89: (+)-beta-caryophyllene synthase
This is an abbreviated version!
For detailed information about (+)-beta-caryophyllene synthase, go to the full flat file.
Reaction
Synonyms
(E)-beta-caryophyllene synthase, BCS, beta-caryophyllene synthase, CsSesquiTPS6a, CsSesquiTPS6b, CsSesquiTPS6c, DcTPS1, E-(beta)-caryophyllene synthase, GcoA, More, OkBCS, PlCAHS, PnCPS, PnTPS1, RtTPS1, RtTPS3, SQS6a, SQS6b, SQS7, TPS1, tps23, TPS3, VvGwECar2, WtDcTPS
ECTree
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Substrates Products
Substrates Products on EC 4.2.3.89 - (+)-beta-caryophyllene synthase
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REACTION DIAGRAM
(+)-beta-caryophyllene + diphosphate
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(2E,6E)-farnesyl diphosphate
(+)-beta-caryophyllene + diphosphate
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(2E,6E)-farnesyl diphosphate
(+)-beta-caryophyllene + diphosphate
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(2E,6E)-farnesyl diphosphate
(+)-beta-caryophyllene + diphosphate
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beta-caryophyllene + diphosphate
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(2E,6E)-farnesyl diphosphate
beta-caryophyllene + diphosphate
the enzyme stereochemistry is not determined in the publication. Recombinant enzyme OkBCS converts farnesyl diphosphate to beta-caryophyllene as a major product (94%) and 6% alpha-humulene
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(2E,6E)-farnesyl diphosphate
beta-caryophyllene + diphosphate
the enzyme stereochemistry is not determined in the publication
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(2E,6E)-farnesyl diphosphate
beta-caryophyllene + diphosphate
the enzyme stereochemistry is not determined in the publication, the reaction mechanism includes a 1,10-ring closure
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(2E,6E)-farnesyl diphosphate
beta-caryophyllene + diphosphate
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(+)-beta-caryophyllene + diphosphate
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(2E,6E)-farnesyl diphosphate + H2O
(+)-beta-caryophyllene + diphosphate
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GC-MS analysis is used for compound identification
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additional information
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GC-MS analysis is used for compound identification
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GC-MS analysis is used for compound identification
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enzyme OkBCS is not active with geranyl diphosphate (GPP) as substrate, besides a weak hydrolysis activity converting GPP to geraniol, identification of substrates and products by GC-MS analysis
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additional information
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the recombinant enzyme catalyses the formation of a major product (E)-beta-caryophyllene (82%) and a minor product alpha-humulene (18%) from farnesyl diphosphate
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the enzyme encoded by gene TPS1 produces beta-caryophyllene as a main product and humulene as a minor compound, and thus is named caryophyllene synthase (PnCPS)
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steady-state kinetic parameters are determined using malachite green phosphate assay
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enzyme VGwECar2 catalyzes the cyclization of farnesyl diphosphate to both beta-caryophyllene and alpha-humulene, plus a small amount of germacrene D, GC-MS analysis
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