4.2.3.82: alpha-santalene synthase
This is an abbreviated version!
For detailed information about alpha-santalene synthase, go to the full flat file.
Word Map on EC 4.2.3.82
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4.2.3.82
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terpene
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sandalwood
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sesquiterpene
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santalols
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synthases
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santalum
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album
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mevalonate
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clausena
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lansium
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pyrophosphate
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fed-batch
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cyclization
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sesquiterpenoids
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monoterpene
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heartwood
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unigenes
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sassy
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bergamotene
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synthesis
- 4.2.3.82
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terpene
- sandalwood
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sesquiterpene
-
santalols
- synthases
- santalum
- album
- mevalonate
- clausena
- lansium
- pyrophosphate
-
fed-batch
-
cyclization
- sesquiterpenoids
-
monoterpene
-
heartwood
-
unigenes
- sassy
-
bergamotene
- synthesis
Reaction
Synonyms
SanSyn, santalene synthase, SaSSy, SspiSy, SSy, SuSSy, Tps2-1
ECTree
4.2.3.82 alpha-santalene synthaseAdvanced search results
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results (Substrates Products
Substrates Products on EC 4.2.3.82 - alpha-santalene synthase
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SUBSTRATE 
PRODUCT
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate)
(Substrate)
LITERATURE
(Substrate)
(Substrate)
COMMENTARY
(Product)
(Product)
LITERATURE
(Product)
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
r=reversible
ir=irreversible
?=not specified
2 (2E,6E)-farnesyl diphosphate
(+)-alpha-santalene + trans-alpha-bergamotene + 2 diphosphate
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amounts of the sesquiterpenes alpha-santalene and trans-alpha-bergamotene produced are,respectively,1.45 and0.177 mg/l
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?
(2E,6E)-farnesyl diphosphate
(+)-alpha-santalene + diphosphate
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-
-
?
(2E,6E)-farnesyl diphosphate
(+)-alpha-santalene + diphosphate
-
-
-
?
(2E,6E)-farnesyl diphosphate
(+)-alpha-santalene + diphosphate
when incubated in the presence of 10 mM Mg2+ the enzyme converts (2E,6E)-farnesyl diphosphate into alpha-santalene, beta-santalene and epi-beta-santalene,alpha-exo-bergamotene, as well as traces of alpha-farnesene and beta-farnesene. Incubations with Mn2+ yields mainly alpha-exo-bergamotene
-
-
?
(2E,6E)-farnesyl diphosphate
(+)-alpha-santalene + diphosphate
when incubated in the presence of 10 mM Mg2+ the enzyme converts (2Z,6Z)-farnesyl diphosphate into alpha-endo-bergamotene, alpha-santalene, (Z)-beta-farnesene, epi-beta-santalene and beta-santalene
-
-
?
(2E,6E)-farnesyl diphosphate
(+)-alpha-santalene + diphosphate
-
-
-
?
(2E,6E)-farnesyl diphosphate
(+)-alpha-santalene + diphosphate
when incubated in the presence of 10 mM Mg2+ the enzyme converts (2E,6E)-farnesyl diphosphate into alpha-santalene, beta-santalene and epi-beta-santalene,alpha-exo-bergamotene, as well as traces of alpha-farnesene and beta-farnesene. Incubations with Mn2+ yields mainly alpha-exo-bergamotene
-
-
?
(2E,6E)-farnesyl diphosphate
(+)-alpha-santalene + diphosphate
-
-
-
?
(2E,6E)-farnesyl diphosphate
(+)-alpha-santalene + diphosphate
when incubated in the presence of 10 mM Mg2+ the enzyme converts (2E,6E)-farnesyl diphosphate into alpha-santalene, beta-santalene and epi-beta-santalene,alpha-exo-bergamotene, as well as traces of alpha-farnesene and beta-farnesene. Incubations with Mn2+ yields mainly alpha-exo-bergamotene
-
-
?
(2E,6E)-farnesyl diphosphate
alpha-santalene + diphosphate
-
products are alpha-santalene, beta-, and epi-beta-santalene, exo-alpha-bergamotene, as well as traces of alpha- and beta-farnesene
-
?
(2E,6E)-farnesyl diphosphate
alpha-santalene + diphosphate
-
synthesis of a mixture of sesquiterpenes namely alpha-santalene, beta-santalene, epi-beta-santalene and alpha-bergamotene
-
?
(2E,6E)-farnesyl diphosphate
alpha-santalene + diphosphate
-
products are alpha-santalene, beta-, and epi-beta-santalene, alpha-exo-bergamotene, as well as traces of alpha- and beta-farnesene
-
?
(2E,6E)-farnesyl diphosphate
alpha-santalene + diphosphate
-
products are alpha-santalene, beta-, and epi-beta-santalene, alpha-exo-bergamotene, as well as traces of alpha- and beta-farnesene
-
?
additional information
?
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the enzyme produces high amonuts of (+)-alpha-santalene from (2E,6E)-farnesyl diphosphate, and traces of (-)-exo-alpha-bergamotene
-
-
?
additional information
?
-
-
the enzyme produces high amonuts of (+)-alpha-santalene from (2E,6E)-farnesyl diphosphate, and traces of (-)-exo-alpha-bergamotene
-
-
?
additional information
?
-
the enzyme produces high amonuts of alpha-santalene from (2E,6E)-farnesyl diphosphate, and traces of (-)-exo-alpha-bergamotene. The enzyme assay is coupled to the inorganic diphosphatase (IPP1) from Saccharomyces cerevisiae. Compound identification and quantification by GC-MS and NMR analysis
-
-
?
additional information
?
-
-
the enzyme produces high amonuts of alpha-santalene from (2E,6E)-farnesyl diphosphate, and traces of (-)-exo-alpha-bergamotene. The enzyme assay is coupled to the inorganic diphosphatase (IPP1) from Saccharomyces cerevisiae. Compound identification and quantification by GC-MS and NMR analysis
-
-
?
additional information
?
-
Santalum album Ssy also accepts (2Z,6Z)-farnesyl diphosphate as substrate, producing a mixture of alpha-endo-bergamotene, alpha-santalene, (Z)-beta-farnesene, epi-beta-santalene, and beta-santalene. With substrate geranyl diphosphate, products are linalool, geraniol, and terpineol along with traces of alpha-pinene and camphene. The product profile resulting from incubations of SaSSy with (E,E)-FPP resembles the authentic essential oil of Santalum album more closely than that of the (Z,Z)-FPP incubations
-
-
?
additional information
?
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Santalum album Ssy also accepts (2Z,6Z)-farnesyl diphosphate as substrate, producing a mixture of alpha-endo-bergamotene, alpha-santalene, (Z)-beta-farnesene, epi-beta-santalene, and beta-santalene. With substrate geranyl diphosphate, products are linalool, geraniol, and terpineol along with traces of alpha-pinene and camphene
-
-
?
additional information
?
-
the enzyme produces high amounts of (+)-alpha-santalene and (-)-beta-santalene, also (-)-exo-alpha-bergamotene, and low amounts of (-)-epi-beta-santalene from (2E,6E)-farnesyl diphosphate
-
-
?
additional information
?
-
the enzyme produces high amounts of (+)-alpha-santalene and (-)-beta-santalene, also (-)-exo-alpha-bergamotene, and low amounts of (-)-epi-beta-santalene from (2E,6E)-farnesyl diphosphate. The enzyme assay is coupled to the inorganic diphosphatase (IPP1) from Saccharomyces cerevisiae. Compound identification and quantification by GC-MS and NMR analysis
-
-
?
additional information
?
-
Santalum austrocaledonicum Ssy also accepts (2Z,6Z)-farnesyl diphosphate as substrate, producing a mixture of endo-alpha-bergamotene, alpha-santalene, (Z)-beta-farnesene, epi-beta-santalene, and beta-santalene. With substrate geranyl diphosphate, products are linalool, geraniol, and terpineol along with traces of alpha-pinene and camphene
-
-
?
additional information
?
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Santalum spicatum Ssy also accepts (2Z,6Z)-farnesyl diphosphate as substrate, producing a mixture of endo-alpha-bergamotene, alpha-santalene, (Z)-beta-farnesene, epi-beta-santalene, and beta-santalene. With substrate geranyl diphosphate, products are linalool, geraniol, and terpineol along with traces of alpha-pinene and camphene
-
-
?
additional information
?
-
the enzyme produces (+)-alpha-santalene, (-)-beta-santalene, and (-)-exo-alpha-bergamotene, and traces of (-)-epi-beta-santalene from (2E,6E)-farnesyl diphosphate
-
-
?
additional information
?
-
the enzyme produces high amonuts of (+)-alpha-santalene and (-)-exo-alpha-bergamotene, also (-)-beta-santalene, and traces of (-)-epi-beta-santalene from (2E,6E)-farnesyl diphosphate. The enzyme assay is coupled to the inorganic diphosphatase (IPP1) from Saccharomyces cerevisiae. Compound identification and quantification by GC-MS and NMR analysis
-
-
?
