4.2.3.81: exo-alpha-bergamotene synthase
This is an abbreviated version!
For detailed information about exo-alpha-bergamotene synthase, go to the full flat file.
Word Map on EC 4.2.3.81
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4.2.3.81
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sandalwood
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terpene
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album
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youth
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santalum
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santalene
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psychometric
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fragrance
- 4.2.3.81
- sandalwood
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terpene
- album
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youth
- santalum
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santalene
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psychometric
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fragrance
Reaction
Synonyms
CoTPS2, LaBERS, SaSSy, SspiSy, SSy, SuSSy, TPS10, TPS2
ECTree
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Natural Substrates Products
Natural Substrates Products on EC 4.2.3.81 - exo-alpha-bergamotene synthase
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REACTION DIAGRAM
(-)-exo-alpha-bergamotene + diphosphate
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(2E,6E)-farnesyl diphosphate
(-)-exo-alpha-bergamotene + diphosphate
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(2E,6E)-farnesyl diphosphate
(-)-exo-alpha-bergamotene + diphosphate
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(2E,6E)-farnesyl diphosphate
(-)-exo-alpha-bergamotene + diphosphate
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(2E,6E)-farnesyl diphosphate
(-)-exo-alpha-bergamotene + diphosphate
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(2E,6E)-farnesyl diphosphate
(-)-exo-alpha-bergamotene + diphosphate
after herbivory by lepidopteran larvae, maize releases a mixture of volatiles that is highly attractive to females of various parasitic wasp species. The terpene synthase TPS10 forms (E)-beta-farnesene, (E)-alpha-bergamotene, and other herbivory-induced sesquiterpene hydrocarbons from the substrate farnesyl diphosphate
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exo-alpha-bergamotene + diphosphate
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products are alpha-santalene, beta-, and epi-beta-santalene, exo-alpha-bergamotene, as well as traces of alpha- and beta-farnesene
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(2E,6E)-farnesyl diphosphate
exo-alpha-bergamotene + diphosphate
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products are alpha-santalene, beta-, and epi-beta-santalene, exo-alpha-bergamotene, as well as traces of alpha- and beta-farnesene
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(2E,6E)-farnesyl diphosphate
exo-alpha-bergamotene + diphosphate
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products are alpha-santalene, beta-, and epi-beta-santalene, alpha-exo-bergamotene, as well as traces of alpha- and beta-farnesene
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enzyme CoTPS2 is multifunctional and novel TPS that catalyses the synthesis of three sesquiterpenes, beta-ylangene, beta-copaene, and beta-cubebene
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additional information
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Santalum album Ssy also accepts (2Z,6Z)-farnesyl diphosphate as substrate, producing a mixture of endo-alpha-bergamotene, alpha-santalene, (Z)-beta-farnesene, epi-beta-santalene, and beta-santalene. With substrate geranyl diphosphate, products are linalool, geraniol, and terpineol along with traces of alpha-pinene and camphene. The product profile resulting from incubations of SaSSy with (6E,6E)-farnesyl diphosphate resembles the authentic essential oil of Santalum album more closely than that of the (6Z,6Z)-farnesyl diphosphate incubations
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additional information
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Santalum album Ssy also accepts (2Z,6Z)-farnesyl diphosphate as substrate, producing a mixture of endo-alpha-bergamotene, alpha-santalene, (Z)-beta-farnesene, epi-beta-santalene, and beta-santalene. With substrate geranyl diphosphate, products are linalool, geraniol, and terpineol along with traces of alpha-pinene and camphene. The product profile resulting from incubations of SaSSy with (6E,6E)-farnesyl diphosphate resembles the authentic essential oil of Santalum album more closely than that of the (6Z,6Z)-farnesyl diphosphate incubations
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additional information
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Santalum austrocaledonicum Ssy also accepts (2Z,6Z)-farnesyl diphosphate as substrate, producing a mixture of endo-alpha-bergamotene, alpha-santalene, (Z)-beta-farnesene, epi-beta-santalene, and beta-santalene. With substrate geranxyl diphosphate, products are linalool, geraniol, and terpineol along with traces of alpha-pinene and camphene
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additional information
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Santalum austrocaledonicum Ssy also accepts (2Z,6Z)-farnesyl diphosphate as substrate, producing a mixture of endo-alpha-bergamotene, alpha-santalene, (Z)-beta-farnesene, epi-beta-santalene, and beta-santalene. With substrate geranxyl diphosphate, products are linalool, geraniol, and terpineol along with traces of alpha-pinene and camphene
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additional information
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Santalum spicatum Ssy also accepts (2Z,6Z)-farnesyl diphosphate as substrate, producing a mixture of endo-alpha-bergamotene, alpha-santalene, (Z)-beta-farnesene, epi-beta-santalene, and beta-santalene. With substrate geranyl diphosphate, products are linalool, geraniol, and terpineol along with traces of alpha-pinene and camphene
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