4.2.3.73: valencene synthase

This is an abbreviated version!
For detailed information about valencene synthase, go to the full flat file.

Word Map on EC 4.2.3.73

4.2.3.73

sesquiterpene

+-valencene

citrus

flavor

terpenoids

nootkatensis

aroma

synthesis

mevalonate

+-nootkatone

sesquiterpenoids

carotenoid

grapefruit

cypress

squalene

heartwood

muticus

hyoscyamus

mandarin

vinifera

murcott

alaska

n-dodecane

grapevine

fragrance

germacrene

Reaction

Synonyms

(+)-valencene synthase, CsTPS1, terpene synthase 1, TPS1, Val, ValCS, VitiM4670, VvVal

ECTree

4 Lyases

4.2 Carbon-oxygen lyases

4.2.3 Acting on phosphates

4.2.3.73 valencene synthase

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Results	in table
14	AA Sequence
5	Application
5	Cloned(Commentary)
4	Expression
1	kcat/KM [mM/s]
1	KM Value [mM]
1	Metals/Ions
2	Molecular Weight [Da]
6	Natural Substrates/ Products (Substrates)
15	Organism
2	Pathway
1	pH Optimum
1	pI Value
1	Reaction
14	Reference
21	Source Tissue
15	Substrates and Products (Substrate)
3	Subunits
13	Synonyms
1	Systematic Name
1	Temperature Optimum [°C]
1	Turnover Number [1/s]

Reference

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Reference on EC 4.2.3.73 - valencene synthase

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663043

Luecker, J.; Bowen, P.; Bohlmann, J.

Vitis vinifera terpenoid cyclases: functional identification of two sesquiterpene synthase cDNAs encoding (+)-valencene synthase and (-)-germacrene D synthase and expression of mono- and sesquiterpene synthases in grapevine flowers and berries

Phytochemistry

2649-2659

2004

Vitis vinifera, Vitis vinifera (Q6Q3H2), Vitis vinifera cv. Gewuerztraminer

15464152

712936

Farhi, M.; Marhevka, E.; Masci, T.; Marcos, E.; Eyal, Y.; Ovadis, M.; Abeliovich, H.; Vainstein, A.

Harnessing yeast subcellular compartments for the production of plant terpenoids

Metab. Eng.

474-481

2011

Citrus sinensis (Q71MJ3)

21601648

713276

Sharon-Asa, L.; Shalit, M.; Frydman, A.; Bar, E.; Holland, D.; Or, E.; Lavi, U.; Lewinsohn, E.; Eyal, Y.

Citrus fruit flavor and aroma biosynthesis: isolation, functional characterization, and developmental regulation of Cstps1, a key gene in the production of the sesquiterpene aroma compound valencene

Plant J.

664-674

2003

Citrus sinensis (Q71MJ3)

14617067

713408

Martin, D.M.; Toub, O.; Chiang, A.; Lo, B.C.; Ohse, S.; Lund, S.T.; Bohlmann, J.

The bouquet of grapevine (Vitis vinifera L. cv. Cabernet Sauvignon) flowers arises from the biosynthesis of sesquiterpene volatiles in pollen grains

Proc. Natl. Acad. Sci. USA

106

7245-7250

2009

Vitis vinifera (Q6Q3H2), Vitis vinifera L. cv. Cabernet Sauvignon (Q6Q3H2)

19359488

729081

Scholtmeijer, K.; Cankar, K.; Beekwilder, J.; Woesten, H.A.; Lugones, L.G.; Bosch, D.

Production of (+)-valencene in the mushroom-forming fungus S. commune

Appl. Microbiol. Biotechnol.

5059-5068

2014

Callitropsis nootkatensis (V9N2L5)

24531273

730098

Frohwitter, J.; Heider, S.; Peters-Wendisch, P.; Beekwilder, J.; Wendisch, V.

Production of the sesquiterpene (+)-valencene by metabolically engineered Corynebacterium glutamicum

J. Biotechnol.

191

205-213

2014

Citrus sinensis (Q71MJ3), Citrus sinensis, Callitropsis nootkatensis (V9N2L5), Callitropsis nootkatensis

24910970

730580

Beekwilder, J.; van Houwelingen, A.; Cankar, K.; van Dijk, A.D.; de Jong, R.M.; Stoopen, G.; Bouwmeester, H.; Achkar, J.; Sonke, T.; Bosch, D.

Valencene synthase from the heartwood of Nootka cypress (Callitropsis nootkatensis) for biotechnological production of valencene

Plant Biotechnol. J.

174-182

2014

Callitropsis nootkatensis (V9N2L5), Callitropsis nootkatensis

24112147

747012

Guo, X.; Sun, J.; Li, D.; Lu, W.

Heterologous biosynthesis of (+)-nootkatone in unconventional yeast Yarrowia lipolytica

Biochem. Eng. J.

137

125-131

2018

Callitropsis nootkatensis

747366

Cankar, K.; Jongedijk, E.; Klompmaker, M.; Majdic, T.; Mumm, R.; Bouwmeester, H.; Bosch, D.; Beekwilder, J.

(+)-Valencene production in Nicotiana benthamiana is increased by down-regulation of competing pathways

Biotechnol. J.

180-189

2015

Callitropsis nootkatensis (S4SC87)

25159317

747426

Yu, Q.; Plotto, A.; Baldwin, E.; Bai, J.; Huang, M.; Yu, Y.; Dhaliwal, H.; Gmitter, F.J.

Proteomic and metabolomic analyses provide insight into production of volatile and non-volatile flavor components in mandarin hybrid fruit

BMC Plant Biol.

2015

Citrus reticulata

25848837

748328

Shen, S.L.; Yin, X.R.; Zhang, B.; Xie, X.L.; Jiang, Q.; Grierson, D.; Chen, K.S.

CitAP2.10 activation of the terpene synthase CsTPS1 is associated with the synthesis of (+)-valencene in Newhall orange

J. Exp. Bot.

4105-4115

2016

Citrus sinensis

27194737