4.2.3.7: pentalenene synthase
This is an abbreviated version!
For detailed information about pentalenene synthase, go to the full flat file.
Word Map on EC 4.2.3.7
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4.2.3.7
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cyclization
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sesquiterpene
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carbocation
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terpenoids
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synthases
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pyrophosphate
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cyclases
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terpene
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isopentenyl
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tricyclic
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pentalenolactone
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lividans
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humulene
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allylic
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anti-markovnikov
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proposals
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synthesis
- 4.2.3.7
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cyclization
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sesquiterpene
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carbocation
-
terpenoids
- synthases
- pyrophosphate
- cyclases
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terpene
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isopentenyl
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tricyclic
- pentalenolactone
- lividans
- humulene
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allylic
-
anti-markovnikov
-
proposals
- synthesis
Reaction
Synonyms
EC 4.6.1.5, PenA, pentalenene synthase, pentalenene synthetase, synthetase, pentalenene
ECTree
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Substrates Products
Substrates Products on EC 4.2.3.7 - pentalenene synthase
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REACTION DIAGRAM
additional information
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isotopically sensitive branching experiments support a mechanism for pentalenene formation involving a 7-protoilludyl cation intermediate
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-
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(2E,6E)-farnesyl diphosphate
pentalenene + diphosphate
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-
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?
(2E,6E)-farnesyl diphosphate
pentalenene + diphosphate
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-
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?
(2E,6E)-farnesyl diphosphate
pentalenene + diphosphate
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-
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?
pentalenene + diphosphate
the study describes theoretical studies on the cyclization reaction
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-
?
2-trans,6-trans-farnesyl diphosphate
pentalenene + diphosphate
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farnesyl diphosphate
pentalenene + diphosphate
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mutant H309A produces 81% pentalenene and 13.4% Delta6-protoilludene, accompanied by minor quantities of germacrene A
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?
farnesyl diphosphate
pentalenene + diphosphate
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the initial step in the reaction is probably a cyclization of farnesyl diphosphate to form humulene
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?
farnesyl diphosphate
pentalenene + diphosphate
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trans,trans
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?
farnesyl diphosphate
pentalenene + diphosphate
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the initial step in the reaction is probably a cyclization of farnesyl diphosphate to form humulene
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?
farnesyl diphosphate
pentalenene + diphosphate
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trans,trans
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?