4.2.3.69: (+)-alpha-barbatene synthase

This is an abbreviated version!
For detailed information about (+)-alpha-barbatene synthase, go to the full flat file.

Reaction

Synonyms

At5g44630, TPS11

ECTree

     4 Lyases

         4.2 Carbon-oxygen lyases

             4.2.3 Acting on phosphates

                4.2.3.69 (+)-alpha-barbatene synthase

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Results	in table
1	AA Sequence
1	Application
2	Cloned(Commentary)
1	General Information
1	Inhibitors
1	KM Value [mM]
1	Metals/Ions
1	Molecular Weight [Da]
2	Natural Substrates/ Products (Substrates)
3	Organism
1	Pathway
1	pI Value
1	Protein Variants
1	Reaction
3	Reference
3	Source Tissue
5	Substrates and Products (Substrate)
1	Subunits
2	Synonyms
1	Systematic Name

Substrates Products

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Substrates Products on EC 4.2.3.69 - (+)-alpha-barbatene synthase

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SUBSTRATE

PRODUCT                       

REACTION DIAGRAM

ORGANISM

UNIPROT

COMMENTARY
(Substrate)

LITERATURE
(Substrate)

COMMENTARY
(Product)

LITERATURE
(Product)

Reversibility
r=reversible
ir=irreversible
?=not specified

(2E,6E)-farnesyl diphosphate

(+)-alpha-barbatene + diphosphate

2 entries

farnesyl diphosphate

alpha-barbatene + diphosphate

Arabidopsis thaliana

Q4KSH9

-

666632

main products, 27.3% alpha-barbatene, 17.8% thujopsene, and 9.9% b-chamigrene, plus 13 minor products

-

?

additional information

?

-

3 entries

(2E,6E)-farnesyl diphosphate

(+)-alpha-barbatene + diphosphate

Arabidopsis thaliana

Q4KSH9

-

713277

further products are: (+)-thujopsene + isobazzanene + (+)-beta-barbatene + E -beta-farnesene + beta-acoradiene + (+)-beta-chamigrene + alpha-zingiberene + alpha-cuprenene + alpha-chamigrene + (–)-cuparene + (–)-?-bisabolene + beta-sesquiphellandrene + delta-cuprenene

-

?

(2E,6E)-farnesyl diphosphate

(+)-alpha-barbatene + diphosphate

Nicotiana benthamiana

-

-

748905

-

-

?

additional information

?

-

Arabidopsis thaliana

Q4KSH9

no substrate: geranyl diphosphate, geranylgeranyl diphosphate

666632

-

-

?

additional information

?

-

Arabidopsis thaliana

Q4KSH9

in vitro catalyses the reaction of geranyl diphosphate to myrcene + limonene + (Z)-beta-ocimene + (E)-beta-ocimene + terpinolene + alpha-terpineol. Formation of these compounds by the enzyme in vivo is rather unlikely, as the protein lacks a transit peptide and is therefore not expected to be present in plastids, where GPP is thought to be produced

713277

-

-

?

additional information

?

-

Arabidopsis thaliana

-

in vitro catalyses the reaction of geranyl diphosphate to myrcene + limonene + (Z)-beta-ocimene + (E)-beta-ocimene + terpinolene + alpha-terpineol. Formation of these compounds by the enzyme in vivo is rather unlikely, as the protein lacks a transit peptide and is therefore not expected to be present in plastids, where GPP is thought to be produced

713277

-

-

?