4.2.3.64: (+)-epicubenol synthase

This is an abbreviated version!
For detailed information about (+)-epicubenol synthase, go to the full flat file.

Reaction

Synonyms

gecA, SGR_6065

ECTree

4 Lyases

4.2 Carbon-oxygen lyases

4.2.3 Acting on phosphates

4.2.3.64 (+)-epicubenol synthase

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Results	in table
1	AA Sequence
1	Cloned(Commentary)
1	Expression
1	kcat/KM [mM/s]
1	KM Value [mM]
2	Natural Substrates/ Products (Substrates)
23	Organism
2	Purification (Commentary)
3	Reaction
11	Reference
1	Specific Activity [micromol/min/mg]
11	Substrates and Products (Substrate)
2	Synonyms
1	Systematic Name
1	Turnover Number [1/s]

Reference

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Reference on EC 4.2.3.64 - (+)-epicubenol synthase

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711376

Cane, D.E.; Ke, N.

Epicubenol synthase. Origin of the oxygen atom of a bacterial sesquiterpene alcohol

Bioorg. Med. Chem. Lett.

105-107

2000

Streptomyces sp., Streptomyces sp. LL-B7

10673090

712231

Cane, D.; Tandon, M.; Prabhakaran, P.

Epicubenol synthase and the enzymatic cyclization of farnesyl diphosphate

J. Am. Chem. Soc.

115

8103-8106

1993

Streptomyces sp., Streptomyces sp. LL-B7

712232

Cane, D.; Tandon, M.

Epicubenol synthase and the stereochemistry of the enzymatic cyclization of farnesyl and nerolidyl diphosphate

J. Am. Chem. Soc.

117

5602-5603

1995

Streptomyces sp., Streptomyces sp. LL-B7

712564

Nabeta, K.; Kigure, K.; Fujita, M.; Nagoya, T.; Ishikawa, T.; Okuyama, H.; Takasawa, T.

Biosynthesis of (+)-cubenene and (+)-epicubenol by cell-free extracts of cultured cells of Heteroscyphus planus and cyclization of [ 2H]farnesyl diphosphates

J. Chem. Soc.

1935-1939

1995

Heteroscyphus planus

712565

Nabeta, K.; Fujita, M.; Komuro, K.; Katayama, K.; Takasawa, T.

In vitro biosynthesis of cadinanes by cell-free extracts of cultured cells of Heteroscyphus planus

J. Chem. Soc.

2065-2070

1997

Heteroscyphus planus

713526

Cane, D.; Tandon, M.

Biosynthesis of (+)-epicubenol

Tetrahedron Lett.

5355-5358

1994

Streptomyces sp., Streptomyces sp. LL-B7

729904

Nakano, C.; Tezuka, T.; Horinouchi, S.; Ohnishi, Y.

Identification of the SGR6065 gene product as a sesquiterpene cyclase involved in (+)-epicubenol biosynthesis in Streptomyces griseus

J. Antibiot.

551-558

2012

Streptomyces griseus (B1W477), Streptomyces griseus

22872183