4.2.3.62: (-)-gamma-cadinene synthase [(2Z,6E)-farnesyl diphosphate cyclizing]
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For detailed information about (-)-gamma-cadinene synthase [(2Z,6E)-farnesyl diphosphate cyclizing], go to the full flat file.
Reaction
Synonyms
TPS, TpsNY
ECTree
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Natural Substrates Products on EC 4.2.3.62 - (-)-gamma-cadinene synthase [(2Z,6E)-farnesyl diphosphate cyclizing]
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REACTION DIAGRAM
(2Z, 6E)-farnesyl diphosphate
(-)-gamma-cadinene + diphosphate
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formation of gamma-cadinene involves a 1,3-hydride shift. (-)-gamma-Cadinene is directly formed from 2Z,6E-farnesyl diphosphate by intramolecular electrophilic attack of the primary carbocation on the C-10 position of farnesyl diphosphate. Second product: (+)-germacrene D
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