4.2.3.55: (S)-beta-bisabolene synthase
This is an abbreviated version!
For detailed information about (S)-beta-bisabolene synthase, go to the full flat file.
Word Map on EC 4.2.3.55
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4.2.3.55
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terpene
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sesquiterpene
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trehalose
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gpa
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aphid
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jasmonate
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monoterpene
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zingiber
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peach
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ginger
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officinale
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persicae
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phytoalexins
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infestation
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defenses
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myzus
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trehalose-6-phosphate
- 4.2.3.55
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terpene
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sesquiterpene
- trehalose
- gpa
- aphid
- jasmonate
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monoterpene
- zingiber
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peach
- ginger
- officinale
- persicae
-
phytoalexins
-
infestation
-
defenses
-
myzus
- trehalose-6-phosphate
Reaction
Synonyms
bisabolene synthase, Os08g07100, SaBS, TPS11, TPS6
ECTree
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Substrates Products
Substrates Products on EC 4.2.3.55 - (S)-beta-bisabolene synthase
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REACTION DIAGRAM
(2Z,6E)-farnesyl diphosphate
(S)-beta-bisabolene + diphosphate
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The synthesis of (S)-beta-macrocarpene from (2E,6E)-farnesyl diphosphate proceeds in two steps. The first step is the cyclization to (S)-beta-bisabolene. The second step is the isomerization to (S)-beta-macrocarpene ((S)-beta-macrocarpene synthase). Product is identified by GC-MS
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(S)-beta-bisabolene + diphosphate
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products of Oryza sativa Os08g07100 gene product are 2.5% 7-epi-sesquithujene, 5.7% (E)-alpha-bergamotene, 5.7% sesquiabinene A, 11.9% (E)-beta-farnesene, 1.5% gamma-curcumene, 30.1% zingiberene, 12.3% beta-bisabolene, 19.1% beta-sesquiphellandrene, 11.2% (E)-gamma-bisabolene
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(2E,6E)-farnesyl diphosphate
(S)-beta-bisabolene + diphosphate
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(2E,6E)-farnesyl diphosphate
(S)-beta-bisabolene + diphosphate
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The synthesis of (S)-beta-macrocarpene from (2E,6E)-farnesyl diphosphate proceeds in two steps. The first step is the cyclization to (S)-beta-bisabolene. The second step is the isomerization to (S)-beta-macrocarpene ((S)-beta-macrocarpene synthase). Product is identified by GC-MS
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(2E,6E)-farnesyl diphosphate
(S)-beta-bisabolene + diphosphate
the enzyme may be involved in plant defense
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(2E,6E)-farnesyl diphosphate
(S)-beta-bisabolene + diphosphate
the enzyme may be involved in plant defense
i.e. ((4S)-1-methyl-4-(5-methyl-1-methylidenehex-4-en-1-yl)cyclohexene
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product identification by GC-MS analysis
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additional information
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no activity with geranylgeranyl diphosphate. TPS6 accepts the monoterpene precursor geranyl diphosphate but the monoterpene products are produced at a lower velocity
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additional information
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no activity with geranylgeranyl diphosphate. TPS6 accepts the monoterpene precursor geranyl diphosphate but the monoterpene products are produced at a lower velocity
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