4.2.3.51: beta-phellandrene synthase (neryl-diphosphate-cyclizing)

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Word Map on EC 4.2.3.51

4.2.3.51

tomato

trichomes

monoterpenes

synthases

solanum

lycopersicum

glandular

herbivore

sesquiterpene

blend

geranylgeranyl

planta

agriculture

Reaction

Synonyms

(E)-beta-phellandrene synthase, beta-phellandrene synthase, beta-PHLS, monoterpene synthase PHS1, phellandrene synthase 1, PHLS, PHS1, TPS20

ECTree

4 Lyases

4.2 Carbon-oxygen lyases

4.2.3 Acting on phosphates

4.2.3.51 beta-phellandrene synthase (neryl-diphosphate-cyclizing)

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Results	in table
1	AA Sequence
1	Application
4	Cloned(Commentary)
1	Expression
1	General Information
1	kcat/KM [mM/s]
1	KM Value [mM]
2	Localization
5	Natural Substrates/ Products (Substrates)
6	Organism
1	Pathway
1	Reaction
6	Reference
2	Source Tissue
7	Substrates and Products (Substrate)
12	Synonyms
1	Systematic Name
1	Turnover Number [1/s]

Substrates Products

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Substrates Products on EC 4.2.3.51 - beta-phellandrene synthase (neryl-diphosphate-cyclizing)

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5 neryl diphosphate

5 diphosphate + alpha-phellandrene + beta-phellandrene + alpha-terpinene + beta-terpinene + limonene

Solanum lycopersicum

C1K5M3

706501

main product is beta-phellandrene. The profile of monoterpenes produced by PHS1 is identical with the monoterpenes found in type VI glandular trichome. In tomato glands, neryl diphosphate serves as a precursor for the synthesis of monoterpenes

neryl diphosphate

beta-phellandrene + diphosphate

3 entries

neryl diphosphate

diphosphate + beta-phellandrene + alpha-terpinene + beta-terpinene + limonene + alpha-phellandrene

Solanum lycopersicum

C1K5M3

neryl diphosphate most likely ionizes to a neryl cation, which can further isomerize to an alpha-terpinyl cation. Further transformations of this cyclic intermediate can eventually yield all observed products of PHS1

706501

the main product is beta-phellandrene

additional information

2 entries