4.2.3.47: beta-farnesene synthase
This is an abbreviated version!
For detailed information about beta-farnesene synthase, go to the full flat file.
Word Map on EC 4.2.3.47
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4.2.3.47
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synthases
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terpenoids
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monoterpene
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diterpene
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geranyl
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linalool
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gpp
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herbivory
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scent
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fragrance
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limonene
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sesquiterpenoids
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germacrene
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carbocation
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sesterterpene
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myrcene
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herbivore-induced
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e-nerolidol
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e-beta-farnesene
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dimethylallyl
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1,8-cineole
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enemy
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sabinene
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5-epi-aristolochene
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bouquet
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ddxxd
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e,e-farnesyl
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pinene
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terpinolene
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agriculture
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multiproduct
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oleoresin
- 4.2.3.47
- synthases
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terpenoids
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monoterpene
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diterpene
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geranyl
- linalool
- gpp
- herbivory
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scent
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fragrance
- limonene
- sesquiterpenoids
- germacrene
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carbocation
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sesterterpene
- myrcene
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herbivore-induced
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e-nerolidol
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e-beta-farnesene
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dimethylallyl
- 1,8-cineole
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enemy
- sabinene
- 5-epi-aristolochene
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bouquet
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ddxxd
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e,e-farnesyl
- pinene
- terpinolene
- agriculture
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multiproduct
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oleoresin
Reaction
Synonyms
(E)-alpha-farnesene synthase, (E)-beta-farnesene synthase, acyclic sesquiterpene synthase, betaFS, betaFS1, betaFS2, CJFS, EbetaF, EbetaF synthase, farnesene synthase, Os08g07100, sesquiterpene synthase, terpene synthase, terpene synthase 10, terpene synthase 10-B73, terpene synthase 10-per, terpene synthase T0, terpene synthase TPS10, TPS10, TPS10-dip, TPS5
ECTree
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Substrates Products
Substrates Products on EC 4.2.3.47 - beta-farnesene synthase
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REACTION DIAGRAM
(2Z,6E)-2-fluorofarnesyl diphosphate
(E)-beta-2-fluorofarnesene + diphosphate
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(3RS)-trans-nerolidyl diphosphate
(E)-beta-farnesene + diphosphate
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-
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?
(E)-beta-farnesene + diphosphate
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-
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?
(2E,6E)-farnesyl diphosphate
(E)-beta-farnesene + diphosphate
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-
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?
(2E,6E)-farnesyl diphosphate
(E)-beta-farnesene + diphosphate
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products of Oryza sativa Os08g07100 gene product are 2.5% 7-epi-sesquithujene, 5.7% (E)-alpha-bergamotene, 5.7% sesquiabinene A, 11.9% (E)-beta-farnesene, 1.5% gamma-curcumene, 30.1% zingiberene, 12.3% beta-bisabolene, 19.1% beta-sesquiphellandrene, 11.2% (E)-gamma-bisabolene
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?
(2E,6E)-farnesyl diphosphate
(E)-beta-farnesene + diphosphate
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single product
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?
(2E,6E)-farnesyl diphosphate
(E)-beta-farnesene + diphosphate
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?
(2E,6E)-farnesyl diphosphate
(E)-beta-farnesene + diphosphate
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?
(2E,6E)-farnesyl diphosphate
(E)-beta-farnesene + diphosphate
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-
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?
(2E,6E)-farnesyl diphosphate
(E)-beta-farnesene + diphosphate
maize plants attacked by lepidopteran larvae emit a volatile mixture that consists mostly of the sesquiterpene olefins, (E)-alpha-bergamotene and (E)-beta-farnesene. These volatiles are produced by the herbivore-induced terpene synthase TPS10 and attract natural enemies to the damaged plants. The TPS10 products (E)-alpha-bergamotene and (E)-beta-farnesene are consistently induced by herbivory, indicating that release of TPS10 volatiles is a defense trait conserved among maize and its wild relatives
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?
(2E,6E)-farnesyl diphosphate
(E)-beta-farnesene + diphosphate
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-
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?
(2E,6E)-farnesyl diphosphate
(E)-beta-farnesene + diphosphate
maize plants attacked by lepidopteran larvae emit a volatile mixture that consists mostly of the sesquiterpene olefins, (E)-alpha-bergamotene and (E)-beta-farnesene. These volatiles are produced by the herbivore-induced terpene synthase TPS10 and attract natural enemies to the damaged plants. The TPS10 products (E)-alpha-bergamotene and (E)-beta-farnesene are consistently induced by herbivory, indicating that release of TPS10 volatiles is a defense trait conserved among maize and its wild relatives
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-
?
(2E,6E)-farnesyl diphosphate
(E)-beta-farnesene + diphosphate
maize plants attacked by lepidopteran larvae emit a volatile mixture that consists mostly of the sesquiterpene olefins, (E)-alpha-bergamotene and (E)-beta-farnesene. These volatiles are produced by the herbivore-induced terpene synthase TPS10 and attract natural enemies to the damaged plants. The TPS10 products (E)-alpha-bergamotene and (E)-beta-farnesene are consistently induced by herbivory, indicating that release of TPS10 volatiles is a defense trait conserved among maize and its wild relatives
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?
(E)-beta-farnesene + diphosphate
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61% (E)-beta-farnesene, by-products: (3E,6E)-alpha-farnesene (26%), (3Z,6E)-alpha-farnesene (6.8%), neroliol (4.9%), and farnesol (1.8%)
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?
farnesyl diphosphate
(E)-beta-farnesene + diphosphate
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61% (E)-beta-farnesene, by-products: (3E,6E)-alpha-farnesene (26%), (3Z,6E)-alpha-farnesene (6.8%), neroliol (4.9%), and farnesol (1.8%)
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?
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geranyl diphosphate is not a substrate for the recombinant enzyme
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additional information
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geranyl diphosphate is not a substrate for the recombinant enzyme
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additional information
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stepwise reaction mechanism through enzyme-bound allylic cationic intermediates. The elimination reaction can proceed via the enzyme-bound intermediate trans-nerolidyl diphosphate
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additional information
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no substrate: geranyl diphosphate, geranyl geranyl diphosphate
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additional information
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CYP170A1 posseses two distinct active sites that catalyze two very different and probably unrelated biochemical activities: beta-farnesene synthase and albaflavenone synthase (monooxygenase activity)
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additional information
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CYP170A1 posseses two distinct active sites that catalyze two very different and probably unrelated biochemical activities: beta-farnesene synthase and albaflavenone synthase (monooxygenase activity)
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