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4.2.3.16: (4S)-limonene synthase

This is an abbreviated version!
For detailed information about (4S)-limonene synthase, go to the full flat file.

Word Map on EC 4.2.3.16

Reaction

geranyl diphosphate
=
(S)-limonene
+
diphosphate

Synonyms

(-)-limonene synthase, (4S)-LS, ag9, CsTPS1, EC 4.1.99.10, limonene synthase, LS, MsLS, PsTPS-Lim

ECTree

     4 Lyases
         4.2 Carbon-oxygen lyases
             4.2.3 Acting on phosphates
                4.2.3.16 (4S)-limonene synthase

Natural Substrates Products

Natural Substrates Products on EC 4.2.3.16 - (4S)-limonene synthase

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NATURAL SUBSTRATE
NATURAL PRODUCT
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
REVERSIBILITY
r=reversible
ir=irreversible
?=not specified
geranyl diphosphate
(-)-(4S)-limonene + diphosphate
show the reaction diagram
geranyl diphosphate
(S)-limonene + diphosphate
show the reaction diagram
-
important step in the biosynthesis of perillaldehyde
-
-
?
geranyl diphosphate
limonene + diphosphate
show the reaction diagram
-
step 3 and 4 of monoterpene biosynthesis, geranyl diphosphate is first ionized and isomerized to produce linalyl diphosphate, which either produces the acyclic monoterpenes or the alpha-terpinyl cation, the universal intermediate for cyclic monoterpenes and transformation of the parent structures to various derivatives
limonene is a cyclic monoterpene, minor constituent of the spike lavender oil
-
?
additional information
?
-
-
overexpression of the LS does not alter the photosynthetic pigment content of spike lavender leaves
-
-
?