4.2.3.153: (5-formylfuran-3-yl)methyl phosphate synthase
This is an abbreviated version!
For detailed information about (5-formylfuran-3-yl)methyl phosphate synthase, go to the full flat file.
Reaction
2 D-glyceraldehyde 3-phosphate = + + 2 H2O
Synonyms
2-furaldehyde phosphate synthase, 4-(hydroxymethyl)-2-furancarboxaldehyde-phosphate synthase, 4-HFC-P synthase, EC 4.1.99.21, mfnB, MJ1099
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Reaction
Reaction on EC 4.2.3.153 - (5-formylfuran-3-yl)methyl phosphate synthase
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2 D-glyceraldehyde 3-phosphate = (5-formylfuran-3-yl)methyl phosphate + phosphate + 2 H2O
a phosphate elimination reaction and a triose phosphate isomerase-like reaction occur at the glyceraldehyde 3-phosphate binding site I and II, respectively, prior to the aldol condensation between the enzyme-bound enol form of methylglyoxal and dihydroxyacetone phosphate, after which the catalytic cycle is completed by a cyclization and two dehydration reactions assisted by several general acids/bases at the same active site
2 D-glyceraldehyde 3-phosphate = (5-formylfuran-3-yl)methyl phosphate + phosphate + 2 H2O
a phosphate elimination reaction and a triose phosphate isomerase-like reaction occur at the glyceraldehyde 3-phosphate binding site I and II, respectively, prior to the aldol condensation between the enzyme-bound enol form of methylglyoxal and dihydroxyacetone phosphate, after which the catalytic cycle is completed by a cyclization and two dehydration reactions assisted by several general acids/bases at the same active site
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