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4.2.3.129: (+)-sativene synthase

This is an abbreviated version!
For detailed information about (+)-sativene synthase, go to the full flat file.

Reaction

(2E,6E)-farnesyl diphosphate
=
(+)-sativene
+
diphosphate

Synonyms

Cop4, sesquiterpene synthase

ECTree

     4 Lyases
         4.2 Carbon-oxygen lyases
             4.2.3 Acting on phosphates
                4.2.3.129 (+)-sativene synthase

Substrates Products

Substrates Products on EC 4.2.3.129 - (+)-sativene synthase

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SUBSTRATE
PRODUCT                       
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
(2E,6E)-farnesyl diphosphate
(+)-sativene + diphosphate
show the reaction diagram
(2Z,6E)-farnesyl diphosphate
(+)-sativene + diphosphate
show the reaction diagram
conversion of (E,E)-farnesyl diphosphate proceeds via a (6S)-beta-bisabolene carbocation in the case of Cop4
-
-
?
additional information
?
-
Cop4 cultures produce several sesquiterpene compounds, e.g. beta-cubebene, sativene, beta-copaene, and cubebol
-
-
?