4.2.3.114: gamma-terpinene synthase

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For detailed information about gamma-terpinene synthase, go to the full flat file.

Word Map on EC 4.2.3.114

4.2.3.114

monoterpene

citrus

synthases

cyclases

cyclization

limonene

unshiu

gpp

satsuma

terpenoids

diterpene

mandarin

beta-pinene

thymol

sesquiterpene

carvacrol

synthesis

Reaction

Synonyms

CitMTSL61, ClcTS, Os04g27790, OsTPS24, OvTPS2, RPS2, terpene synthase 24, TPS1, TPS2, TPS4, TvTPS, TvTPS1, TvTPS2

ECTree

4 Lyases

4.2 Carbon-oxygen lyases

4.2.3 Acting on phosphates

4.2.3.114 gamma-terpinene synthase

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Results	in table
23	AA Sequence
1	Application
1	CAS Registry Number
8	Cloned(Commentary)
2	Crystallization (Commentary)
2	Expression
7	General Information
1	General Stability
4	IC50 Value
6	Inhibitors
6	KM Value [mM]
6	Localization
12	Metals/Ions
5	Molecular Weight [Da]
5	Natural Substrates/ Products (Substrates)
16	Organism
6	pH Optimum
2	pH Range
3	pI Value
2	Protein Variants
4	Purification (Commentary)
4	Reaction
16	Reference
14	Source Tissue
1	Specific Activity [micromol/min/mg]
1	Storage Stability
20	Substrates and Products (Substrate)
5	Subunits
16	Synonyms
1	Systematic Name
4	Temperature Optimum [°C]

Systematic Name

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Systematic Name on EC 4.2.3.114 - gamma-terpinene synthase

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geranyl-diphosphate diphosphate-lyase (cyclizing, gamma-terpinene-forming)

Isolated from Thymus vulgaris (thyme) [1,2], Citrus limon (lemon) [3], Citrus unshiu (satsuma) [4] and Origanum vulgare (oregano) [5]. Requires Mg2+. Mn2+ less effective. The reaction involves a 1,2-hydride shift. The 5-pro-S hydrogen of geranyl diphosphate is lost. Traces of several other monoterpenoids are formed in addition to gamma-terpinene.