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4.2.3.102: sesquithujene synthase

This is an abbreviated version!
For detailed information about sesquithujene synthase, go to the full flat file.

Reaction

(2E,6E)-farnesyl diphosphate
=
sesquithujene
+
diphosphate

Synonyms

TPS5, TPS5-Del1

ECTree

     4 Lyases
         4.2 Carbon-oxygen lyases
             4.2.3 Acting on phosphates
                4.2.3.102 sesquithujene synthase

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Resultsin table
1AA Sequence
1Cloned(Commentary)
3Metals/Ions
1Organism
1Purification (Commentary)
1Reaction
1Reference
2Source Tissue
2Substrates and Products (Substrate)
2Synonyms
1Systematic Name

Substrates Products

Substrates Products on EC 4.2.3.102 - sesquithujene synthase

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SUBSTRATE
PRODUCT                       
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
(2E,6E)-farnesyl diphosphate
sesquithujene + diphosphate
show the reaction diagram
-
-
sesquithujene is the major product, the enzyme also produces (S)-beta-bisabolene, and the minor products 7-epi-sesquithujene, (Z)-alpha-bergamotene, (E)-alpha-bergamotene, sesquisabinene B, sesquisabinene A, and (E)-beta-farnesene
-
?
geranyl diphosphate
(S)-(-)-limonene + diphosphate
show the reaction diagram
-
-
main product is (S)-(-)-limonene, minor products are alpha-thujene, beta-myrcene, (+)-sabinene, (-)-sabinene, alpha-terpinene, (E)-beta-ocimene, beta-phellandrene, alpha-terpinolene, gamma-terpinene, sabinene hydrate, (R)-(-)-linalool, and (S)-(1)-linalool
-
?