4.2.1.B9: colneleic acid/etheroleic acid synthase

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For detailed information about colneleic acid/etheroleic acid synthase, go to the full flat file.

Reaction

(9S,10E,12Z)-9-hydroperoxy-10,12-octadecadienoate

(8E)-9-[(1E,3Z)-nona-1,3-dien-1-yloxy]non-8-enoate

Synonyms

13/9-DES, 13/9-divinyl ether synthase, 9/13-DES, 9/13-divinyl ether synthase, etheroleic acid/colneleic acid synthase, More

ECTree

4 Lyases

4.2 Carbon-oxygen lyases

4.2.1 Hydro-lyases

4.2.1.B9 colneleic acid/etheroleic acid synthase

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Results	in table
1	AA Sequence
1	Cloned(Commentary)
1	Cofactor
1	Expression
4	kcat/KM [mM/s]
4	KM Value [mM]
1	Localization
2	Molecular Weight [Da]
1	Natural Substrates/ Products (Substrates)
1	Organism
1	pH Optimum
1	Purification (Commentary)
2	Reaction
1	Reference
3	Source Tissue
5	Substrates and Products (Substrate)
1	Subunits
6	Synonyms
1	Systematic Name
4	Turnover Number [1/s]

Natural Substrates Products

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of the Enzyme Summary Page.

Natural Substrates Products on EC 4.2.1.B9 - colneleic acid/etheroleic acid synthase

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(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate

(9Z,11E)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + H2O

Allium sativum

Q2WE96

the prominent divinyl ether in garlic is the 13-lipoxygenase-derived etheroleic acid. Expression in Arabidopsis shows that 9-lipoxygenase-derived colnelenic acid dominates 24 h after wounding

704870

i.e. etheroleic acid