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4.2.1.B8: etheroleic acid synthase

This is an abbreviated version!
For detailed information about etheroleic acid synthase, go to the full flat file.

Reaction

(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate
=
(9Z,11E)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid
+
H2O

Synonyms

CYP74M3, CYP74Q1, DES, divinyl ether synthase, SmDES2

ECTree

     4 Lyases
         4.2 Carbon-oxygen lyases
             4.2.1 Hydro-lyases
                4.2.1.B8 etheroleic acid synthase

KCat KM Value

KCat KM Value on EC 4.2.1.B8 - etheroleic acid synthase

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kcat/KM VALUE [1/mMs-1]
SUBSTRATE
ORGANISM
UNIPROT
COMMENTARY hide
LITERATURE
IMAGE
0.0007 - 2676.3
(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoic acid
0.0031
(9Z,11E,13S,15Z)-13-hydroperoxy-9,11,15-octadecatrienate
-
pH 7.5, 25°C
2986.6
(9Z,11E,13S,15Z)-13-hydroperoxy-9,11,15-octadecatrienoic acid
pH 7.5, 25°C, recombinant enzyme