4.2.1.168: GDP-4-dehydro-6-deoxy-alpha-D-mannose 3-dehydratase

This is an abbreviated version!
For detailed information about GDP-4-dehydro-6-deoxy-alpha-D-mannose 3-dehydratase, go to the full flat file.

Reaction

Synonyms

colD, GDP-4-keto-6-deoxy-D-mannose-3-dehydratase, WbdK

ECTree

     4 Lyases

         4.2 Carbon-oxygen lyases

             4.2.1 Hydro-lyases

                4.2.1.168 GDP-4-dehydro-6-deoxy-alpha-D-mannose 3-dehydratase

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Results	in table
30	AA Sequence
1	Cloned(Commentary)
1	Cofactor
3	Crystallization (Commentary)
1	General Information
4	Organism
2	Pathway
2	Protein Variants
4	Reaction
4	Reference
5	Substrates and Products (Substrate)
5	Synonyms
1	Systematic Name

Reaction

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Reaction on EC 4.2.1.168 - GDP-4-dehydro-6-deoxy-alpha-D-mannose 3-dehydratase

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REACTION

REACTION DIAGRAM

COMMENTARY

ORGANISM

UNIPROT

LITERATURE

2-GDP-[(2S,3S,6R)-5-amino-6-methyl-3,6-dihydro-2H-pyran-3-ol] = 2-GDP-[(2S,3S,6R)-5-imino-6-methyloxan-3-ol]

(1b), spontaneous

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GDP-2-[(2S,3S,6R)-5-imino-6-methyloxan-3-ol] + H2O = GDP-4-dehydro-3,6-dideoxy-alpha-D-mannose + NH3

(1c), spontaneous

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GDP-4-dehydro-alpha-D-rhamnose + L-glutamate = 2-GDP-[(2S,3S,6R)-5-amino-6-methyl-3,6-dihydro-2H-pyran-3-ol] + 2-oxoglutarate + H2O

(1a)

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GDP-4-dehydro-alpha-D-rhamnose + L-glutamate = GDP-4-dehydro-3,6-dideoxy-alpha-D-mannose + 2-oxoglutarate + NH3

overall reaction

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