4.2.1.159: dTDP-4-dehydro-6-deoxy-alpha-D-glucopyranose 2,3-dehydratase
This is an abbreviated version!
For detailed information about dTDP-4-dehydro-6-deoxy-alpha-D-glucopyranose 2,3-dehydratase, go to the full flat file.
Reaction
Synonyms
D-olivose, D-oliose and D-mycarose 2,3-dehydratase, EryBV, evaA, jadO, megBVI, mtmV, oleV, spnO, TDP-4-keto-6-deoxy-D-glucose 2,3-dehydratase
ECTree
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Systematic Name
Systematic Name on EC 4.2.1.159 - dTDP-4-dehydro-6-deoxy-alpha-D-glucopyranose 2,3-dehydratase
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dTDP-4-dehydro-6-deoxy-alpha-D-glucopyranose hydro-lyase (dTDP-(2R,6S)-2,4-dihydroxy-6-methyl-2,6-dihydropyran-3-one-forming)
The enzyme participates in the biosynthesis of several deoxysugars, including beta-L-4-epi-vancosamine, alpha-L-megosamine, L- and D-olivose, D-oliose, D-mycarose, forosamine and beta-L-digitoxose. In vitro the intermediate can undergo a spontaneous decomposition to maltol [2,3].