4.2.1.100: cyclohexa-1,5-dienecarbonyl-CoA hydratase

This is an abbreviated version!
For detailed information about cyclohexa-1,5-dienecarbonyl-CoA hydratase, go to the full flat file.

Reaction

Synonyms

1,5-dienoyl-CoA hydratase, cyclohexa-1,5-diene-1-carbonyl-CoA hydratase, Cyclohexa-1,5-diene-1-carboxyl-CoA hydratase, DCH, dienoyl-CoA hydratase, EC 4.2.1.102, Ferp_1031

ECTree

     4 Lyases

         4.2 Carbon-oxygen lyases

             4.2.1 Hydro-lyases

                4.2.1.100 cyclohexa-1,5-dienecarbonyl-CoA hydratase

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Results	in table
86	AA Sequence
1	CAS Registry Number
4	Cloned(Commentary)
6	General Information
4	KM Value [mM]
11	Molecular Weight [Da]
14	Natural Substrates/ Products (Substrates)
13	Organism
7	Pathway
1	pH Optimum
4	Purification (Commentary)
1	Reaction
1	Reaction Type
13	Reference
4	Source Tissue
10	Specific Activity [micromol/min/mg]
28	Substrates and Products (Substrate)
4	Subunits
17	Synonyms
1	Systematic Name
2	Temperature Optimum [°C]
3	Turnover Number [1/s]

Substrates Products

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Substrates Products on EC 4.2.1.100 - cyclohexa-1,5-dienecarbonyl-CoA hydratase

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SUBSTRATE

PRODUCT                       

REACTION DIAGRAM

ORGANISM

UNIPROT

COMMENTARY
(Substrate)

LITERATURE
(Substrate)

COMMENTARY
(Product)

LITERATURE
(Product)

Reversibility
r=reversible
ir=irreversible
?=not specified

2-fluorocyclohexa-1,5-diene-1-carbonyl-CoA + H2O

2-fluoro-6-hydroxycyclohexa-1-ene-1-carbonyl-CoA

2 entries

6-fluorocyclohexa-1,5-diene-1-carbonyl-CoA + H2O

6-fluoro-6-hydroxycyclohexa-1-ene-1-carbonyl-CoA

2 entries

6-hydroxycyclohexa-1-ene-1-carbonyl-CoA

cyclohexa-1,5-diene-1-carbonyl-CoA + H2O

2 entries

cyclohex-1-ene-1-carbonyl-CoA + H2O

2-hydroxycyclohexane-1-carbonyl-CoA

Thauera aromatica

-

-

285200

-

285200

?

cyclohexa-1,5-diene-1-carbonyl-CoA + H2O

6-hydroxycyclohex-1-ene-1-carbonyl-CoA

8 entries

cyclohexa-1,5-diene-1-carbonyl-CoA + H2O

6-hydroxycyclohex-1-enecarbonyl-CoA

8 entries

cyclohexa-1,5-diene-1-carbonyl-CoA + H2O

6-hydroxycyclohexa-1-ene-1-carbonyl-CoA

Thauera aromatica

o87873

-

747850

-

-

r

cyclohexa-1,5-dienecarbonyl-CoA + H2O

6-hydroxycyclohex-1-ene-1-carbonyl-CoA

Thauera aromatica

o87873

trans-1,4 water addition, stereochemistry of 6-hydroxycyclohex-1-ene-1-carboxyl-CoA by NMR analysis

692753

-

-

?

cyclohexa-2,5-diene-1-carbonyl-CoA + H2O

6-hydroxycyclohex-2-ene-1-carbonyl-CoA

Thauera aromatica

-

only when dithionite is used as an artificial electron donor

285200

-

285200

?

additional information

?

-

2 entries

2-fluorocyclohexa-1,5-diene-1-carbonyl-CoA + H2O

2-fluoro-6-hydroxycyclohexa-1-ene-1-carbonyl-CoA

Thauera aromatica

o87873

-

747850

-

-

r

2-fluorocyclohexa-1,5-diene-1-carbonyl-CoA + H2O

2-fluoro-6-hydroxycyclohexa-1-ene-1-carbonyl-CoA

Thauera aromatica K172

o87873

-

747850

-

-

r

6-fluorocyclohexa-1,5-diene-1-carbonyl-CoA + H2O

6-fluoro-6-hydroxycyclohexa-1-ene-1-carbonyl-CoA

Thauera aromatica

o87873

-

747850

-

-

r

6-fluorocyclohexa-1,5-diene-1-carbonyl-CoA + H2O

6-fluoro-6-hydroxycyclohexa-1-ene-1-carbonyl-CoA

Thauera aromatica K172

o87873

-

747850

-

-

r

6-hydroxycyclohexa-1-ene-1-carbonyl-CoA

cyclohexa-1,5-diene-1-carbonyl-CoA + H2O

Thauera aromatica

o87873

-

747850

-

-

r

6-hydroxycyclohexa-1-ene-1-carbonyl-CoA

cyclohexa-1,5-diene-1-carbonyl-CoA + H2O

Thauera aromatica K172

o87873

-

747850

-

-

r

cyclohexa-1,5-diene-1-carbonyl-CoA + H2O

6-hydroxycyclohex-1-ene-1-carbonyl-CoA

Aromatoleum evansii

-

-

207952

-

207952

?

cyclohexa-1,5-diene-1-carbonyl-CoA + H2O

6-hydroxycyclohex-1-ene-1-carbonyl-CoA

Ferroglobus placidus

D3RXI0

-

729651

-

-

?

cyclohexa-1,5-diene-1-carbonyl-CoA + H2O

6-hydroxycyclohex-1-ene-1-carbonyl-CoA

Ferroglobus placidus

D3RXI0

the enzyme is involved in benzoyl-coenzyme A degradation

729651

-

-

?

cyclohexa-1,5-diene-1-carbonyl-CoA + H2O

6-hydroxycyclohex-1-ene-1-carbonyl-CoA

Ferroglobus placidus DSM 10642

D3RXI0

-

729651

-

-

?

cyclohexa-1,5-diene-1-carbonyl-CoA + H2O

6-hydroxycyclohex-1-ene-1-carbonyl-CoA

Ferroglobus placidus DSM 10642

D3RXI0

the enzyme is involved in benzoyl-coenzyme A degradation

729651

-

-

?

cyclohexa-1,5-diene-1-carbonyl-CoA + H2O

6-hydroxycyclohex-1-ene-1-carbonyl-CoA

Thauera aromatica

-

-

285201

-

285201

r

cyclohexa-1,5-diene-1-carbonyl-CoA + H2O

6-hydroxycyclohex-1-ene-1-carbonyl-CoA

Thauera aromatica

o87873

-

747850

-

-

r

cyclohexa-1,5-diene-1-carbonyl-CoA + H2O

6-hydroxycyclohex-1-ene-1-carbonyl-CoA

Thauera aromatica K172

o87873

-

747850

-

-

r

cyclohexa-1,5-diene-1-carbonyl-CoA + H2O

6-hydroxycyclohex-1-enecarbonyl-CoA

Aromatoleum evansii

-

-

207952

-

-

?

cyclohexa-1,5-diene-1-carbonyl-CoA + H2O

6-hydroxycyclohex-1-enecarbonyl-CoA

Desulfococcus multivorans

-

-

680480

-

-

r

cyclohexa-1,5-diene-1-carbonyl-CoA + H2O

6-hydroxycyclohex-1-enecarbonyl-CoA

Desulfococcus multivorans

-

involved in the benzoyl-CoA pathway

680480

-

-

r

cyclohexa-1,5-diene-1-carbonyl-CoA + H2O

6-hydroxycyclohex-1-enecarbonyl-CoA

Geobacter metallireducens

-

-

680480

-

-

r

cyclohexa-1,5-diene-1-carbonyl-CoA + H2O

6-hydroxycyclohex-1-enecarbonyl-CoA

Geobacter metallireducens

-

involved in the benzoyl-CoA pathway

680480

-

-

r

cyclohexa-1,5-diene-1-carbonyl-CoA + H2O

6-hydroxycyclohex-1-enecarbonyl-CoA

Syntrophus aciditrophicus

-

-

680480

-

-

r

cyclohexa-1,5-diene-1-carbonyl-CoA + H2O

6-hydroxycyclohex-1-enecarbonyl-CoA

Syntrophus aciditrophicus

-

involved in the benzoyl-CoA pathway

680480

-

-

r

cyclohexa-1,5-diene-1-carbonyl-CoA + H2O

6-hydroxycyclohex-1-enecarbonyl-CoA

Thauera aromatica

-

-

285201

-

-

?

additional information

?

-

Thauera aromatica

o87873

the 1,5-dienoyl-CoA hydratase hydrated the fluorocyclohexa-1,5-dienoyl-CoA isomers to a mixture of the stable 2-fluoro-6-hydroxycyclohexa-1-ene-1-carbonyl-CoA and the unstable alpha-fluorohydrin 6-fluoro-6-hydroxycyclohexa-1-ene-1-carbonyl-CoA. The latter spontaneously decomposed to HF and 6-oxo-cyclohexa-1-ene-1-carbonyl-CoA

747850

-

-

?

additional information

?

-

Thauera aromatica K172

o87873

the 1,5-dienoyl-CoA hydratase hydrated the fluorocyclohexa-1,5-dienoyl-CoA isomers to a mixture of the stable 2-fluoro-6-hydroxycyclohexa-1-ene-1-carbonyl-CoA and the unstable alpha-fluorohydrin 6-fluoro-6-hydroxycyclohexa-1-ene-1-carbonyl-CoA. The latter spontaneously decomposed to HF and 6-oxo-cyclohexa-1-ene-1-carbonyl-CoA

747850

-

-

?