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4.1.2.17: L-fuculose-phosphate aldolase

This is an abbreviated version!
For detailed information about L-fuculose-phosphate aldolase, go to the full flat file.

Word Map on EC 4.1.2.17

Reaction

L-Fuculose 1-phosphate
=
glycerone phosphate
 +
(S)-lactaldehyde

Synonyms

aldolase, L-fuculose phosphate, F-1PA, Fuc-1PA, FucA, fuculose aldolase, fuculose-1-phosphate aldolase, L-Fuc1P aldolase, L-Fuculose 1-phosphate aldolase, L-Fuculose phosphate aldolase, L-Fuculose-1-P aldolase, L-fuculose-1-phosphate aldolase, L-fuculose-phosphate aldolase

ECTree

     4 Lyases
         4.1 Carbon-carbon lyases
             4.1.2 Aldehyde-lyases
                4.1.2.17 L-fuculose-phosphate aldolase

Substrates Products

Substrates Products on EC 4.1.2.17 - L-fuculose-phosphate aldolase

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SUBSTRATE
PRODUCT                       
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
(2R)-2,3-dihydroxy-4-nitrobutanal
(1S,2R,3R,4R,5R,6R)-1-hydroxymethyl-6-nitrocyclohexane-1,2,3,4,5-pentol + (1R,2R,3R,4R,5S,6S)-1-hydroxymethyl-6-nitrocyclohexane-1,2,3,4,5-pentol
show the reaction diagram
-
-
-
?
(2S)-2,3-dihydroxy-4-nitrobutanal
(1R,2R,3R,4S,5S,6S)-1-hydroxymethyl-6-nitrocyclohexane-1,2,3,4,5-pentol + (1S,2R,3S,4S,5R,6R)-1-(hydroxymethyl)-6-nitrocyclohexane-1,2,3,4,5-pentol
show the reaction diagram
-
-
-
?
(S)-Cbz-alaninal + dihydroxyacetone phosphate
(3R,4R,5S)-5-(benzyloxycarbonylamino)-5,6-dideoxy-1-phosphonohex-2-ulose
show the reaction diagram
-
-
-
-
?
3-hydroxy-4-nitrobutanal
(1S,2R,3R,5S,6R)-1-hydroxymethyl-6-nitrocyclohexane-1,2,3,5-tetraol + (1R,2R,3R,5R,6S)-1-hydroxymethyl-6-nitrocyclohexane-1,2,3,5-tetraol
show the reaction diagram
-
-
-
?
4-nitrobutanal
(1R,2R,3S,6S)-1-hydroxymethyl-6-nitrocyclohexane-1,2,3-triol + (1S,2R,3R,6R)-1-hydroxymethyl-6-nitrocyclohexane-1,2,3-triol
show the reaction diagram
-
-
-
?
6-Deoxy-L-sorbose 1-phosphate
?
show the reaction diagram
-
about 5% of the activity with L-fuculose 1-phosphate
-
-
?
D-Fructose 1,6-diphosphate
?
show the reaction diagram
-
about 4% of the activity with L-fuculose 1-phosphate
-
-
?
D-Fructose 1-phosphate
?
show the reaction diagram
-
about 4% of the activity with L-fuculose 1-phosphate
-
-
?
D-ribose 1-phosphate
glycerone phosphate + glycolaldehyde
show the reaction diagram
-
-
-
-
?
D-Ribulose 1,5-diphosphate
?
show the reaction diagram
-
about 6% of the activity with L-fuculose 1-phosphate
-
-
?
dihydroxyacetone + (R)-N-benzyloxycarbonyl-alaninal
5-[[(benzyloxy)carbonyl]amino]-5,6-dideoxy-1-O-phosphonato-D-erythro-hex-2-ulose
show the reaction diagram
-
-
-
-
?
dihydroxyacetone + (S)-N-benzyloxycarbonyl-alaninal
5-[[(benzyloxy)carbonyl]amino]-5,6-dideoxy-1-O-phosphonato-D-erythro-hex-2-ulose
show the reaction diagram
-
-
-
-
?
dihydroxyacetone + benzyl (2R)-2-formylpyrrolidine-1-carboxylate
(3R,4R)-4-[1-[(benzyloxy)carbonyl]pyrrolidin-2-yl]-3,4-dihydroxy-2-oxobutyl phosphate
show the reaction diagram
-
-
-
-
?
dihydroxyacetone + benzyl (2S)-2-formylpyrrolidine-1-carboxylate
(3R,4S)-4-[1-[(benzyloxy)carbonyl]pyrrolidin-2-yl]-3,4-dihydroxy-2-oxobutyl phosphate
show the reaction diagram
-
-
-
-
?
dihydroxyacetone + benzyl [(2R)-3-methyl-1-oxobutan-2-yl]carbamate
(3R,4R,5R)-5-[[(benzyloxy)carbonyl]amino]-3,4-dihydroxy-6-methyl-2-oxoheptyl phosphate
show the reaction diagram
-
-
-
-
?
dihydroxyacetone + benzyl [(2R)-4-methyl-1-oxopentan-2-yl]carbamate
(3R,4R,5R)-5-[[(benzyloxy)carbonyl]amino]-3,4-dihydroxy-7-methyl-2-oxooctyl phosphate
show the reaction diagram
-
-
-
-
?
dihydroxyacetone + benzyl [(2S)-3-methyl-1-oxobutan-2-yl]carbamate
(3R,4R,5R)-5-[[(benzyloxy)carbonyl]amino]-3,4-dihydroxy-6-methyl-2-oxoheptyl phosphate + (3R,4S,5R)-5-[[(benzyloxy)carbonyl]amino]-3,4-dihydroxy-6-methyl-2-oxoheptyl phosphate
show the reaction diagram
-
-
70:30 product ratio
-
?
dihydroxyacetone + benzyl [(2S)-4-methyl-1-oxopentan-2-yl]carbamate
(3R,4R,5R)-5-[[(benzyloxy)carbonyl]amino]-3,4-dihydroxy-7-methyl-2-oxooctyl phosphate
show the reaction diagram
-
-
-
-
?
dihydroxyacetone + benzyl [(3S)-3-methyl-1-oxopentan-2-yl]carbamate
(3R,4R,5R,6S)-5-(((benzyloxy)carbonyl)amino)-3,4-dihydroxy-6-methyl-2-oxooctyl phosphate + (3R,4S,5R,6S)-5-(((benzyloxy)carbonyl)amino)-3,4-dihydroxy-6-methyl-2-oxooctyl phosphate
show the reaction diagram
-
-
78:22 product ratio
-
?
dihydroxyacetone phosphate
methylglyoxal + phosphate
show the reaction diagram
-
-
-
-
?
dihydroxyacetone phosphate + (S)-Cbz-alaninal
?
show the reaction diagram
-
-
-
-
?
dihydroxyacetone phosphate + D-glyceraldehyde
D-psicose 1-phosphate
show the reaction diagram
dihydroxyacetone phosphate + D-glyceraldehyde 3-phosphate
?
show the reaction diagram
-
-
-
-
r
dihydroxyacetone phosphate + DL-glyceraldehyde
L-tagatose 1-phosphate
show the reaction diagram
dihydroxyacetone phosphate + L-glyceraldehyde
L-tagatose 1-phosphate
show the reaction diagram
dihydroxyacetone phosphate + L-lactaldehyde
L-fuculose 1-phosphate
show the reaction diagram
-
-
-
-
r
dihydroxyacetone phosphate + L-lactaldehyde
L-fuculose-1-phosphate
show the reaction diagram
dihydroxyacetone phosphate + N-Cbz-(2R)-2-amino-3-methylbutanal
N-Cbz-5-amino-1,3,4-trihydroxyoctan-2-one
show the reaction diagram
-
wild-type 65% aldol adduct formed, mutant F131A, 76% aldol adduct formed
-
-
?
dihydroxyacetone phosphate + N-Cbz-(2R)-2-amino-4-methylpentanal
N-Cbz-5-amino-1,3,4-trihydroxy-7-methyloctan-2-one
show the reaction diagram
-
-
-
-
?
dihydroxyacetone phosphate + N-Cbz-(2S)-2-amino-3-methylbutanal
N-Cbz-5-amino-1,3,4-trihydroxyoctan-2-one
show the reaction diagram
-
wild-type 48% aldol adduct formed, mutant F131A, 60% aldol adduct formed
-
-
?
dihydroxyacetone phosphate + N-Cbz-(2S)-2-aminopropanal
N-Cbz-5-amino-1,3,4-trihydroxyhexan-2-one
show the reaction diagram
-
wild-type 65% aldol adduct formed, mutant F131A, 64% aldol adduct formed
-
-
?
dihydroxyacetone phosphate + N-Cbz-aminoacetaldehyde
N-Cbz-5-amino-1,3,4-trihydroxypentan-2-one
show the reaction diagram
-
wild-type 63% aldol adduct formed, mutant F131A, 50% aldol adduct formed
-
-
?
dimethoxyacetaldehyde + glycerone phosphate
(3R,4S)-3,4-dihydroxy-5,5-dimethoxy-2-oxopentyl phosphate
show the reaction diagram
-
-
-
?
DL-glycerol 3-phosphate + D-glyceraldehyde
?
show the reaction diagram
DL-glycerol 3-phosphate + dihydroxyacetone phosphate
?
show the reaction diagram
DL-glycerol 3-phosphate + DL-glyceraldehyde
D-psicose 1-phosphate
show the reaction diagram
-
-
-
r
Glycerone phosphate + (R)-lactaldehyde
6-Deoxy-D-psicose 1-phosphate
show the reaction diagram
Glycerone phosphate + (S)-lactaldehyde
L-Fuculose 1-phosphate
show the reaction diagram
glycerone phosphate + D-glyceraldehyde
D-psicose 1-phosphate
show the reaction diagram
glycerone phosphate + D-glyceraldehyde
D-sorbose 1-phosphate
show the reaction diagram
-
-
-
?
glycerone phosphate + DL-glyceraldehyde
?
show the reaction diagram
-
-
-
?
Glycerone phosphate + glycolaldehyde
D-Ribulose 1-phosphate
show the reaction diagram
glycerone phosphate + L-glyceraldehyde
L-fructose 1-phosphate
show the reaction diagram
-
-
-
?
glycerone phosphate + L-glyceraldehyde
L-tagatose 1-phosphate
show the reaction diagram
L-Fuculose 1-phosphate
?
show the reaction diagram
-
initial step in the metabolism of L-fucose
-
-
?
L-fuculose 1-phosphate
dihydroxyacetone phosphate + (S)-lactaldehyde
show the reaction diagram
L-fuculose 1-phosphate
glycerone phosphate + (S)-lactaldehyde
show the reaction diagram
L-glycerol 3-phosphate + D-glyceraldehyde
?
show the reaction diagram
L-glycerol 3-phosphate + D-glyceraldehyde
D-psicose 1-phosphate
show the reaction diagram
-
L-glycerol 3-phosphate i.e. dihydroxyacetone phosphate, i.e. glycerone-3-phosphate
-
-
?
L-glycerol 3-phosphate + glycoaldehyde
D-ribulose 1-phosphate
show the reaction diagram
-
L-glycerol 3-phosphate i.e. dihydroxyacetone phosphate, i.e. glycerone-3-phosphate
-
-
?
L-glycerol 3-phosphate + L-glyceraldehyde
L-tagatose 1-phosphate
show the reaction diagram
-
L-glycerol 3-phosphate i.e. dihydroxyacetone phosphate, i.e. glycerone-3-phosphate
-
-
?
additional information
?
-