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4.1.1.76: arylmalonate decarboxylase

This is an abbreviated version!
For detailed information about arylmalonate decarboxylase, go to the full flat file.

Word Map on EC 4.1.1.76

Reaction

2-aryl-2-methylmalonate
=
2-arylpropanoate
 +
CO2

Synonyms

AMDase, aryl/alkenyl malonate decarboxylase, Arylmalonate decarboxylase, Arylmalonate decarboxylase (Alcaligenes bronchisepticus strain KU 1201), Decarboxylase, arylmalonate, Decarboxylase, arylmalonate (Bordetella bronchiseptica clone pAMD100 reduced), Decarboxylase, arylmalonate (Bordetella bronchiseptica strain KU1201 reduced)

ECTree

     4 Lyases
         4.1 Carbon-carbon lyases
             4.1.1 Carboxy-lyases
                4.1.1.76 arylmalonate decarboxylase

KM Value

KM Value on EC 4.1.1.76 - arylmalonate decarboxylase

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KM VALUE [mM]
SUBSTRATE
ORGANISM
UNIPROT
COMMENTARY hide
LITERATURE
IMAGE
8.2
(1-benzofuran-2-yl)(hydroxy)propanedioic acid
wild type enzyme, pH and temperature not specified in the publication
0.82 - 3.1
(1-benzothiophen-5-yl)(hydroxy)propanedioic acid
3.1
(1-benzothiophen-6-yl)(hydroxy)propanedioic acid
wild type enzyme, pH and temperature not specified in the publication
14.4
(1E)-but-1-en-1-yl(methyl)propanedioic acid
wild type enzyme
12.7
(4,5-dimethylfuran-2-yl)(hydroxy)propanedioic acid
wild type enzyme, pH and temperature not specified in the publication
8.6
(furan-2-yl)(hydroxy)propanedioic acid
wild type enzyme, pH and temperature not specified in the publication
6.09
1-Naphthylmalonate
-
-
10.1
2-(furan-2-yl) malonic acid
wild-type, pH not specified in the publication, temperature not specified in the publication
10.4 - 18.3
2-aryl-2-methylmalonate
4.1 - 30.2
2-hydroxy-2-phenylmalonic acid
22.2 - 26.9
2-methyl-2-phenylmalonate
19.4
2-Naphthylmalonate
-
-
9.9 - 10.7
2-phenyl-2-methylmalonate
3.3 - 7.5
2-phenylmalonate
87.4
2-Thienylmalonate
-
-
0.8 - 7.8
2-vinyl-2-methylmalonic acid
12.5
alpha-Methyl-alpha(2-thienyl)malonate
-
-
1.01 - 14.3
alpha-methyl-alpha-(alpha-thienyl)malonate
0.43 - 1.25
alpha-methyl-alpha-(beta-naphthyl)malonate
25.5
alpha-methyl-alpha-phenylmalonate
-
-
4.3 - 13.3
alpha-phenylmalonate
7.3
hydroxy(2-methylprop-1-en-1-yl)propanedioic acid
wild type enzyme
13.3
hydroxy(4-methylfuran-2-yl)propanedioic acid
wild type enzyme, pH and temperature not specified in the publication
16.1
hydroxy(5-methoxyfuran-2-yl)propanedioic acid
wild type enzyme, pH and temperature not specified in the publication
9.8
hydroxy(5-methylfuran-2-yl)propanedioic acid
wild type enzyme, pH and temperature not specified in the publication
30.2
hydroxy(phenyl)propanedioic acid
wild type enzyme, pH and temperature not specified in the publication
6.4 - 13
hydroxy(pyridin-3-yl)propanedioic acid
2.2 - 4.3
hydroxy(thiophen-2-yl)propanedioic acid
9.1
hydroxy[(1E)-prop-1-en-1-yl]propanedioic acid
wild type enzyme
9.84
m-Chlorophenylmalonate
-
-
35.7
m-Fluorophenylmalonate
-
-
3.5
methyl(2-methylprop-1-en-1-yl)propanedioic acid
wild type enzyme
0.43 - 1.56
methyl(2-naphthyl)malonic acid
5.03 - 14.5
methyl(2-thienyl)malonic acid
26.9
methyl(phenyl)propanedioic acid
wild type enzyme
12.8
methyl[(1E)-prop-1-en-1-yl]propanedioic acid
wild type enzyme
12.6
o-Chlorophenylmalonate
-
-
27.5
o-Fluorophenylmalonate
-
-
8.32
p-Chlorophenylmalonate
-
-
13.5
p-Fluorophenylmalonate
-
-
9.36
p-Methoxyphenylmalonate
-
-
8.89
p-methylphenylmalonate
-
-
0.3 - 123
Phenylmalonate