4.1.1.100: prephenate decarboxylase

This is an abbreviated version!
For detailed information about prephenate decarboxylase, go to the full flat file.

Reaction

Synonyms

aerD, bacA, non-aromatizing prephenate decarboxylase, SalX

ECTree

     4 Lyases

         4.1 Carbon-carbon lyases

             4.1.1 Carboxy-lyases

                4.1.1.100 prephenate decarboxylase

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Results	in table
20	AA Sequence
3	Cloned(Commentary)
4	General Information
3	kcat/KM [mM/s]
2	KM Value [mM]
6	Natural Substrates/ Products (Substrates)
8	Organism
6	Pathway
1	pH Optimum
3	Purification (Commentary)
1	Reaction
6	Reference
12	Substrates and Products (Substrate)
7	Synonyms
1	Systematic Name
2	Turnover Number [1/s]

Natural Substrates Products

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Natural Substrates Products on EC 4.1.1.100 - prephenate decarboxylase

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NATURAL SUBSTRATE

NATURAL PRODUCT

REACTION DIAGRAM

ORGANISM

UNIPROT

COMMENTARY
(Substrate)

LITERATURE
(Substrate)

COMMENTARY
(Product)

LITERATURE
(Product)

REVERSIBILITY
r=reversible
ir=irreversible
?=not specified

prephenate

3-[(4S)-4-hydroxycyclohexa-1,5-dien-1-yl]-2-oxopropanoate + CO2

6 entries

prephenate

3-[(4S)-4-hydroxycyclohexa-1,5-dien-1-yl]-2-oxopropanoate + CO2

Bacillus subtilis

P39638

-

729211

-

-

?

prephenate

3-[(4S)-4-hydroxycyclohexa-1,5-dien-1-yl]-2-oxopropanoate + CO2

Bacillus subtilis

P39638

the enzyme from the bacterium Bacillus subtilis is involved in the biosynthesis of the nonproteinogenic amino acid tetrahydrotyrosine a component of the dipeptide antibiotic bacilysin

729204

-

-

?

prephenate

3-[(4S)-4-hydroxycyclohexa-1,5-dien-1-yl]-2-oxopropanoate + CO2

Bacillus subtilis 168

P39638

the enzyme from the bacterium Bacillus subtilis is involved in the biosynthesis of the nonproteinogenic amino acid tetrahydrotyrosine a component of the dipeptide antibiotic bacilysin

729204

-

-

?

prephenate

3-[(4S)-4-hydroxycyclohexa-1,5-dien-1-yl]-2-oxopropanoate + CO2

Bacillus subtilis 168

P39638

-

729211

-

-

?

prephenate

3-[(4S)-4-hydroxycyclohexa-1,5-dien-1-yl]-2-oxopropanoate + CO2

Planktothrix agardhii

-

the enzyme is involved in the biosynthesis of the nonribosomal glycopeptides aeruginoside 126A and B. These natural products contain the unusual amino acid residue 2-carboxy-6-hydroxy-octahydroindole

729203

the product is non-enzymatically isomerized to the thermodynamically favored conjugated exocyclic diene 3-((1R,4R)-4-hydroxycyclohexa-2-enylidene)-2-oxopropanoate

-

?

prephenate

3-[(4S)-4-hydroxycyclohexa-1,5-dien-1-yl]-2-oxopropanoate + CO2

Salinispora tropica

-

the enzyme is involved in the biosynthetic pathway to the proteasome inhibitor salinosporamide A. SalX is relevant to the production of the nonproteinogenic amino acid building block cyclohexenylalanine

729203

-

-

?