3.5.3.21: methylenediurea deaminase

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For detailed information about methylenediurea deaminase, go to the full flat file.

Word Map on EC 3.5.3.21

3.5.3.21

nitrilase

mandelonitrile

nitril

fluorescens

racemic

cyanide

enantioselectivity

arylacetonitriles

r,s-mandelonitrile

alcaligenes

esculenta

benzaldehyde

enantiospecificity

s-mandelic

faecalis

manihot

s-hydroxynitrile

rhodococcus

r-enantiomer

amidase

cassava

rhodochrous

Reaction

+ 2 H2O =

+ 2 NH3 +

Synonyms

Deiminase, methylenediurea, MDUase, Methylenediurea deiminase, Methylenediurease

ECTree

3 Hydrolases

3.5 Acting on carbon-nitrogen bonds, other than peptide bonds

3.5.3 In linear amidines

3.5.3.21 methylenediurea deaminase

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4	Reaction
1	Reaction Type
3	Reference
3	Specific Activity [micromol/min/mg]
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Systematic Name on EC 3.5.3.21 - methylenediurea deaminase

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methylenediurea aminohydrolase

Methylenediurea is hydrolysed and decarboxylated to give an aminated methylurea, which then spontaneously hydrolyses to hydroxymethylurea. The enzyme from Ochrobactrum anthropi also hydrolyses dimethylenetriurea and trimethylenetetraurea as well as ureidoglycolate, which is hydrolysed to urea and glyoxylate, and allantoate, which is hydrolysed to ureidoglycolate, ammonia and carbon dioxide.