3.3.2.8: limonene-1,2-epoxide hydrolase
This is an abbreviated version!
For detailed information about limonene-1,2-epoxide hydrolase, go to the full flat file.
Word Map on EC 3.3.2.8
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3.3.2.8
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stereoselective
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rhodococcus
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erythropolis
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hydrolases
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desymmetrization
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cyclohexene
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enantioselective
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alphabet
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regioselective
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lining
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six-stranded
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astronomically
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intricacies
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valpromide
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selenomethionine-substituted
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biocatalysis
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single-wavelength
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wide-ranging
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diols
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polyketide
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cyclopentene
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synthesis
- 3.3.2.8
-
stereoselective
- rhodococcus
- erythropolis
- hydrolases
-
desymmetrization
- cyclohexene
-
enantioselective
-
alphabet
-
regioselective
-
lining
-
six-stranded
-
astronomically
-
intricacies
- valpromide
-
selenomethionine-substituted
-
biocatalysis
-
single-wavelength
-
wide-ranging
- diols
- polyketide
-
cyclopentene
- synthesis
Reaction
Synonyms
CH55-LEH, LEH, limA, limonene 1,2-epoxide hydrolase, limonene epoxide hydrolase, limonene oxide hydrolase, limonene-1,2-epoxide hydrolase, Re-LEH, Tomsk-LEH
ECTree
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Systematic Name
Systematic Name on EC 3.3.2.8 - limonene-1,2-epoxide hydrolase
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1,2-epoxymeth-8-ene hydrolase
Involved in the monoterpene degradation pathway of the actinomycete Rhodococcus erythropolis. The enzyme hydrolyses several alicyclic and 1-methyl-substituted epoxides, such as 1-methylcyclohexene oxide, indene oxide and cyclohexene oxide. It differs from the previously described epoxide hydrolases [EC 3.3.2.4 (trans-epoxysuccinate hydrolase), EC 3.3.2.6 (leukotriene-A4 hydrolase), EC 3.3.2.7 (hepoxilin-epoxide hydrolase), EC 3.3.2.9 (microsomal epoxide hydrolase) and EC 3.3.2.10 (soluble epoxide hydrolase)] as it is not inhibited by 2-bromo-4'-nitroacetophenone, diethyl dicarbonate, 4-fluorochalcone oxide or 1,10-phenanthroline. Both enantiomers of menth-8-ene-1,2-diol [i.e. (1R,2R,4S)-menth-8-ene-1,2-diol and (1S,2S,4R)-menth-8-ene-1,2-diol] are metabolized.