3.2.1.125: raucaffricine beta-glucosidase
This is an abbreviated version!
For detailed information about raucaffricine beta-glucosidase, go to the full flat file.
Word Map on EC 3.2.1.125
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3.2.1.125
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strictosidine
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serpentina
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rauvolfia
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indole
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ajmaline
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monoterpenoid
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glucosidases
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glycosides
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deglucosylation
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hydrolases
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secologanin
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pharmacology
- 3.2.1.125
- strictosidine
- serpentina
- rauvolfia
- indole
- ajmaline
-
monoterpenoid
-
glucosidases
- glycosides
-
deglucosylation
- hydrolases
- secologanin
- pharmacology
Reaction
Synonyms
glucosidase, raucaffricine beta-, More, raucaffricine beta-D-glucosidase, raucaffricine glucosidase, raucaffricine O-beta-D-glucosidase, raucaffricine-O-beta-D-glucosidase, RG
ECTree
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Substrates Products
Substrates Products on EC 3.2.1.125 - raucaffricine beta-glucosidase
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REACTION DIAGRAM
1,2,19,20-tetrahydroraucaffricine + H2O
17-O-acetylnorajmaline + D-glucose
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87% of activity compared to raucaffricine
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-
?
1,2-(S)-dihydro-raucaffricine + H2O
2beta(R)-1,2-dihydrovomilenine + D-glucose
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98% acivity compared to raucaffricine
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-
?
1,2-dihydro-1-methylraucaffricine + H2O
acetic acid 3-ethylidene-4-hydroxy-13-methyl-1,3,4,7,8,13,13a,13b-octahydro-2H,6H-2,7-cyclo-6,8a-methano-pyrido[1',2':1,2]azepino[3,4-b]indol-8-yl ester + D-glucose
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36% of activity compared to raucaffricine
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-
?
1-methyl-1,2-dihydroraucaffricine + H2O
?
recombinant RG
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?
17-O-deacetyl-1,2-dihydroraucaffricine + H2O
3-ethylidene-1,3,4,7,8,13,13a,13b-octahydro-2H,6H-2,7-cyclo-6,8a-methano-pyrido[1',2':1,2]azepino[3,4-b]indole-4,8-diol + D-glucose
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95% of activity compared to raucaffricine
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-
?
21-glucopyranosyl-hydroxysarpagan-17-al + H2O
?
recombinant RG
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?
21-glucopyranosyl-hydroxysarpagan-17-ol + H2O
?
recombinant RG
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?
secologanin + H2O
secologanin aglycone
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0.24% acivity compared to raucaffricine
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-
?
strictosidine + H2O
strictosidine aglycone + D-glucose
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1.18% acivity compared to raucaffricine
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-
?
2beta(R)-1,2-dihydrovomilenine + D-glucose
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-
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-
?
1,2-dihydroraucaffricine + H2O
2beta(R)-1,2-dihydrovomilenine + D-glucose
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98% of activity compared to raucaffricine
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-
?
raucaffricine + H2O
D-glucose + vomilenine
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the product vomilenine exists in aqueous solutions in an equilibrium of 21(R)- and 21(S)-vomilenine in a ratio of 3.4:1
?
raucaffricine + H2O
D-glucose + vomilenine
best substrate, highly specific enzyme
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?
raucaffricine + H2O
D-glucose + vomilenine
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involved in the biosynthesis of alkaloids, e.g. ajmaline
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?
raucaffricine + H2O
D-glucose + vomilenine
specifically involved in alkaloid biosynthesis, e.g. ajmaline
vomilene is a direct intermediate in ajmaline biosynthesis
?
strictosidine + H2O
?
only recombinant RG, no substrate of native RG
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?