1.4.1.23: valine dehydrogenase (NAD+)
This is an abbreviated version!
For detailed information about valine dehydrogenase (NAD+), go to the full flat file.
Reaction
Synonyms
VDH, VDH2
ECTree
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Reaction
Reaction on EC 1.4.1.23 - valine dehydrogenase (NAD+)
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L-valine + H2O + NAD+ = 3-methyl-2-oxobutanoate + NH3 + NADH + H+
sequential ordered mechanism with non-competitive inhibition by valine
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L-valine + H2O + NAD+ = 3-methyl-2-oxobutanoate + NH3 + NADH + H+
the reductive amination proceeds through a sequential ordered ternary-binary mechanism. NADH binds to the enzyme first, followed by 2-oxoisovalerate and NH3, and valine is released first, followed by NAD+
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L-valine + H2O + NAD+ = 3-methyl-2-oxobutanoate + NH3 + NADH + H+
sequential ordered mechanism with non-competitive inhibition by valine
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