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1.3.1.27: 2-hexadecenal reductase

This is an abbreviated version!
For detailed information about 2-hexadecenal reductase, go to the full flat file.

Word Map on EC 1.3.1.27

Reaction

hexadecanal
+
NADP+
=
2-trans-hexadecenal
+
NADPH
+
H+

Synonyms

2-alkenal reductase, ALH, hexadecanal: NADP+ oxidoreductase, NADPH-dependent 2-alkenal reductase, reductase, 2-alkenal, zeta-Crystallin, ZmAER

ECTree

     1 Oxidoreductases
         1.3 Acting on the CH-CH group of donors
             1.3.1 With NAD+ or NADP+ as acceptor
                1.3.1.27 2-hexadecenal reductase

Substrates Products

Substrates Products on EC 1.3.1.27 - 2-hexadecenal reductase

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SUBSTRATE
PRODUCT                       
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
1,2-propenal + NAD(P)H
propanal + NAD(P)+
show the reaction diagram
-
-
-
?
1-octen-3-one + NADPH + H+
nonanal + NADP+
show the reaction diagram
-
-
-
-
?
2-cis-hexadecenal + NADPH + H+
hexadecanal + NADP+
show the reaction diagram
-
-
-
-
r
2-nonenal + NADPH + H+
nonanal + NADP+
show the reaction diagram
-
-
-
ir
2-trans,4-trans-hexadienal + NAD(P)H
4-trans-hexenal + NAD(P)+
show the reaction diagram
-
i.e. sorbaldehyde, low reaction rate
-
?
2-trans-hexadecenal + NADPH
hexadecanal + NADP+
show the reaction diagram
2-trans-octadecenal + NADPH
octdecanal + NADP+
show the reaction diagram
-
-
-
r
2-trans-tetradecenal + NADPH
tetradecanal + NADP+
show the reaction diagram
-
-
-
r
3-buten-2-one + NADPH + H+
butan-2-one + NADP+
show the reaction diagram
-
-
-
?
4-hydroxy-2-hexenal + NADPH + H+
4-hydroxyhexadecanal + NADP+
show the reaction diagram
-
-
-
?
4-hydroxy-2-nonenal + NADPH + H+
4-hydroxynonanal + NADP+
show the reaction diagram
-
-
-
?
cis-2-heptenal + NAD(P)H
heptanal + NAD(P)+
show the reaction diagram
-
-
-
?
cis-2-octenal + NAD(P)H
octanal + NAD(P)+
show the reaction diagram
-
best substrate
-
?
trans-2-butenal + NAD(P)H
butanal + NAD(P)+
show the reaction diagram
-
very low reaction rate
-
?
trans-2-cinnamaldehyde + NAD(P)H
cinnamaldehyde + NAD(P)+
show the reaction diagram
-
low reaction rate
-
?
trans-2-decenal + NAD(P)H
decanal + NAD(P)+
show the reaction diagram
trans-2-dodecenal + NAD(P)H
dodecanal + NAD(P)+
show the reaction diagram
-
low reaction rate
-
?
trans-2-heptenal + NAD(P)H
heptanal + NAD(P)+
show the reaction diagram
-
low reaction rate
-
?
trans-2-hexenal + NAD(P)H
hexanal + NAD(P)+
show the reaction diagram
-
low reaction rate
-
?
trans-2-hexenal + NADPH + H+
hexanal + NADP+
show the reaction diagram
-
-
-
-
?
trans-2-nonenal + NAD(P)H + H+
nonanal + NAD(P)+
show the reaction diagram
-
low reaction rate
-
?
trans-2-nonenal + NADPH + H+
nonanal + NADP+
show the reaction diagram
-
-
-
-
?
trans-2-octenal + NAD(P)H
octanal + NAD(P)+
show the reaction diagram
traumatin + NADPH + H+
12-oxododecanoic acid + NADP+
show the reaction diagram
-
i.e. (10E)-12-oxododec-10-enoic acid
-
-
?
additional information
?
-
enzyme additionally catalyzes the reduction of quinones, reaction of EC 1.6.5.5. The enzyme shows a low level of activity with cinnamaldehyde and no activity with 2-cyclohexen-1-one and 15-ketoprostaglandin E2. No activity is detected with nonanal and 2-nonene
-
-
?