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1.14.19.43: palmitoyl-[glycerolipid] 3-(E)-desaturase

This is an abbreviated version!
For detailed information about palmitoyl-[glycerolipid] 3-(E)-desaturase, go to the full flat file.

Word Map on EC 1.14.19.43

Reaction

a 1-acyl-2-palmitoyl-[glycerolipid]
+ 2 reduced ferredoxin [iron-sulfur] cluster +
O2
+ 2 H+ =
a 1-acyl-2-[(3E)-hexadec-3-enoyl]-[glycerolipid]
+ 2 oxidized ferredoxin [iron-sulfur] cluster + 2 H2O

Synonyms

DELTA4 fatty acid desaturase, FAD4, FAD4 desaturase, fatty acid desaturase4, IsFAD4

ECTree

     1 Oxidoreductases
         1.14 Acting on paired donors, with incorporation or reduction of molecular oxygen
             1.14.19 With oxidation of a pair of donors resulting in the reduction of O2 to two molecules of water
                1.14.19.43 palmitoyl-[glycerolipid] 3-(E)-desaturase

Substrates Products

Substrates Products on EC 1.14.19.43 - palmitoyl-[glycerolipid] 3-(E)-desaturase

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SUBSTRATE
PRODUCT                       
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
1-acyl-2-palmitoyl-[glycerolipid] + reduced ferredoxin [iron-sulfur] cluster + O2 + H+
1-acyl-2-[(3E)-hexadec-3-enoyl]-[glycerolipid] + oxidized ferredoxin [iron-sulfur] cluster + H2O
show the reaction diagram
22:4(n-6) + reduced ferredoxin [iron-sulfur] cluster + O2 + H+
docosa-4,7,10,13,16-pentaenoic acid + oxidized ferredoxin [iron-sulfur] cluster + H2O
show the reaction diagram
22:5(n-3) + reduced ferredoxin [iron-sulfur] cluster + O2 + H+
docosa-4,7,10,13,16,19-hexaenoic acid + oxidized ferredoxin [iron-sulfur] cluster + H2O
show the reaction diagram
additional information
?
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desaturation of fatty acid 16:0 to 16:1 by the FAD4 desaturase in the chloroplasts occurs after phosphatidylglycerophosphate dephosphorylation
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?