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1.14.19.23: acyl-lipid (n+3)-(Z)-desaturase (ferredoxin)

This is an abbreviated version!
For detailed information about acyl-lipid (n+3)-(Z)-desaturase (ferredoxin), go to the full flat file.

Word Map on EC 1.14.19.23

Reaction

an oleoyl-[glycerolipid]
+ 2 reduced ferredoxin [iron-sulfur] cluster +
O2
 + 2 H+ =
a linoleoyl-[glycerolipid]
 + 2 oxidized ferredoxin [iron-sulfur] cluster + 2 H2O

Synonyms

acyl-lipid omega6-desaturase (ferredoxin), DELTA-12 desaturase, FAD6, fatty acid desaturase-6, linoleate synthase, n-6 desaturase, oleate desaturase, oleoyl-CoA desaturase, oleoylphosphatidylcholine desaturase, phosphatidylcholine desaturase

ECTree

     1 Oxidoreductases
         1.14 Acting on paired donors, with incorporation or reduction of molecular oxygen
             1.14.19 With oxidation of a pair of donors resulting in the reduction of O2 to two molecules of water
                1.14.19.23 acyl-lipid (n+3)-(Z)-desaturase (ferredoxin)

Substrates Products

Substrates Products on EC 1.14.19.23 - acyl-lipid (n+3)-(Z)-desaturase (ferredoxin)

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SUBSTRATE
PRODUCT                       
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
1,2-di-(9'-cis-octadecenyl)-3-beta-D-galactopyranosyl-sn-glycerol + 2 reduced ferredoxin [iron-sulfur] cluster O2 + 2 H+
?
show the reaction diagram
-
-
-
?
1,2-dioleoyl-3-beta-D-galactopyranosyl-sn-glycerol + 2 reduced ferredoxin [iron-sulfur] cluster + O2 + 2 H+
?
show the reaction diagram
-
-
-
?
1-oleoyl-2-(7'-cis-hexadecenoyl)-3-beta-D-galactopyranosyl-sn-glycerol + 2 reduced ferredoxin [iron-sulfur] cluster + O2 + 2 H+
1-linoleoyl-2-(7'-cis-hexadecenoyl)-3-beta-D-galactopyranosyl-sn-glycerol + 2 oxidized ferredoxin [iron-sulfur] cluster + 2 H2O
show the reaction diagram
-
-
-
?
1-oleoyl-sn-glycerol 3-phosphate + 2 reduced ferredoxin [iron-sulfur] cluster + O2 + 2 H+
1-linoleoyl-sn-glycerol 3-phosphate + 2 reduced ferredoxin [iron-sulfur] cluster + 2 H2O
show the reaction diagram
-
-
-
?
an oleoyl-[glycerolipid] + 2 reduced ferredoxin [iron-sulfur] cluster + O2 + 2 H+
a linoleoyl-[glycerolipid] + 2 oxidized ferredoxin [iron-sulfur] cluster + 2 H2O
show the reaction diagram
an oleoyl-[glycerolipid] + 2 reduced ferredoxin [iron-sulfur] cluster+ O2 + 2 H+
a linoleoyl-[glycerolipid] + 2 oxidized ferredoxin [iron-sulfur] cluster + 2 H2O
show the reaction diagram
-
-
-
?
an oleoyl-[monogalactosyldiacylglycerol] + 2 reduced ferredoxin [iron-sulfur] cluster + O2 + 2 H+
a linoleoyl-[monogalactosyldiacylglycerol] + 2 oxidized ferredoxin [iron-sulfur] cluster + 2 H2O
show the reaction diagram
-
-
-
?
an palmitoleoyl-[glycerolipid] + 2 reduced ferredoxin [iron-sulfur] cluster + O2 + 2 H+
a (9Z,12E)-hexadeca-9,12-dienoyl-[glycerolipid] + 2 oxidized ferredoxin [iron-sulfur] cluster + 2 H2O
show the reaction diagram
the main product arising from desaturation of 16:1(9c) appears to be the 16:2(9,12) isomer and is thus an omega-4 desaturation product rather than an omega-6 desaturation product
-
-
?
erucic acid + 2 reduced ferredoxin [iron-sulfur] cluster + O2 + 2 H+
?
show the reaction diagram
-
-
-
?
oleate + 2 reduced ferredoxin [iron-sulfur] cluster + O2 + 2 H+
linoleate + 2 oxidized ferredoxin [iron-sulfur] cluster + 2 H2O
show the reaction diagram
oleoyl-[glycerolipid] + reduced ferredoxin [iron-sulfur] cluster + O2 + H+
linoleoyl-[glycerolipid] + oxidized ferredoxin [iron-sulfur] cluster + H2O
show the reaction diagram
-
-
-
-
?
additional information
?
-