1.14.15.9: spheroidene monooxygenase

This is an abbreviated version!
For detailed information about spheroidene monooxygenase, go to the full flat file.

Word Map on EC 1.14.15.9

1.14.15.9

rhodobacter

sphaeroides

light-harvesting

spheroidenone

purple

sulfidophilum

rhodovulum

torulene

o-methyltransferase

carotene

rc-lh1-pufx

lycopene

desaturase

pigments

analysis

Reaction

Synonyms

acyclic carotenoid 2-ketolase, CrtA

ECTree

1 Oxidoreductases

1.14 Acting on paired donors, with incorporation or reduction of molecular oxygen

1.14.15 With reduced iron-sulfur protein as one donor, and incorporation of one atom of oxygen into the other donor

1.14.15.9 spheroidene monooxygenase

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Results	in table
59	AA Sequence
1	Application
5	Cloned(Commentary)
1	Cofactor
4	General Information
8	KM Value [mM]
2	Molecular Weight [Da]
1	Natural Substrates/ Products (Substrates)
9	Organism
5	Pathway
2	pH Optimum
3	Purification (Commentary)
13	Reaction
9	Reference
21	Substrates and Products (Substrate)
2	Subunits
9	Synonyms
1	Systematic Name
2	Temperature Optimum [°C]

Reaction

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Reaction on EC 1.14.15.9 - spheroidene monooxygenase

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2',2'-dihydroxy-2-oxospirilloxanthin = 2,2'-dioxospirilloxanthin + H2O

(3c), spontaneous

2'-hydroxy-2-oxospirilloxanthin + reduced ferredoxin [iron-sulfur] cluster + O2 + 2 H+ = 2',2'-dihydroxy-2-oxospirilloxanthin + oxidized ferredoxin [iron-sulfur] cluster + H2O

(3b)

2,2-dihydroxyspheroidene = spheroiden-2-one + H2O

(1c), spontaneous

2,2-dihydroxyspirilloxanthin = 2-oxospirilloxanthin + H2O

(2c), spontaneous

2-hydroxyspheroidene + 2 reduced ferredoxin [iron-sulfur] cluster + O2 + 2 H+ = 2,2-dihydroxyspheroidene + 2 oxidized ferredoxin [iron-sulfur] cluster + H2O

(1b)

2-hydroxyspirilloxanthin + 2 reduced ferredoxin [iron-sulfur] cluster + O2 + 2 H+ = 2,2-dihydroxyspirilloxanthin + 2 oxidized ferredoxin [iron-sulfur] cluster + H2O

(2b)

2-oxospirilloxanthin + 2 reduced ferredoxin [iron-sulfur] cluster + O2 + 2 H+ = 2'-hydroxy-2-oxospirilloxanthin + 2 oxidized ferredoxin [iron-sulfur] cluster + H2O

(3a)

2-oxospirilloxanthin + 4 reduced ferredoxin [iron-sulfur] cluster + 2 O2 = 2,2'-dioxospirilloxanthin + 4 oxidized ferredoxin [iron-sulfur] cluster + 3 H2O

(3)

spheroidene + 2 reduced ferredoxin [iron-sulfur] cluster + O2 + 2 H+ = 2-hydroxyspheroidene + 2 oxidized ferredoxin [iron-sulfur] cluster + H2O

(1a)

spheroidene + 4 reduced ferredoxin [iron-sulfur] cluster + 2 O2 = spheroiden-2-one + 4 oxidized ferredoxin [iron-sulfur] cluster + 3 H2O

2 entries

spirilloxanthin + 2 reduced ferredoxin [iron-sulfur] cluster + O2 + 2 H+ = 2-hydroxyspirilloxanthin + 2 oxidized ferredoxin [iron-sulfur] cluster + H2O

(2a)

spirilloxanthin + 4 reduced ferredoxin [iron-sulfur] cluster + 2 O2 = 2-oxospirilloxanthin + 4 oxidized ferredoxin [iron-sulfur] cluster + 3 H2O

(2)