1.14.14.42: homomethionine N-monooxygenase

This is an abbreviated version!
For detailed information about homomethionine N-monooxygenase, go to the full flat file.

Word Map on EC 1.14.14.42

1.14.14.42

glucosinolates

cyp83a1

brassica

glucoraphanin

cabbage

auxin

ugt74b1

oleraceae

broccoli

methionine-derived

gluconapin

sulforaphane

brassicales

brassicaceae

silique

chain-elongated

oximes

aldoximes

sinigrin

Reaction

an (E)-omega-(methylsulfanyl)alkanal oxime

Synonyms

CYP79F1, CYP79F2, dihomomethionine N-hydroxylase, hexahomomethionine N-hydroxylase

ECTree

1 Oxidoreductases

1.14 Acting on paired donors, with incorporation or reduction of molecular oxygen

1.14.14 With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor

1.14.14.42 homomethionine N-monooxygenase

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Results	in table
3	AA Sequence
4	Cloned(Commentary)
2	Cofactor
1	Crystallization (Commentary)
3	General Information
7	KM Value [mM]
2	Molecular Weight [Da]
10	Natural Substrates/ Products (Substrates)
4	Organism
8	Pathway
1	pI Value
4	Reaction
3	Reference
13	Source Tissue
10	Substrates and Products (Substrate)
2	Subunits
7	Synonyms
1	Systematic Name

Reaction

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Reaction on EC 1.14.14.42 - homomethionine N-monooxygenase

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an L-N,N-dihydroxypolyhomomethionine = an (E)-omega-(methylsulfanyl)alkanal oxime + CO2 + H2O

(1c)

an L-N-hydroxypolyhomomethionine + [reduced NADPH-hemoprotein reductase] + O2 = an L-N,N-dihydroxypolyhomomethionine + [oxidized NADPH-hemoprotein reductase] + H2O

(1b)

an L-polyhomomethionine + 2 [reduced NADPH-hemoprotein reductase] + 2 O2 = an (E)-omega-(methylsulfanyl)alkanal oxime + 2 [oxidized NADPH-hemoprotein reductase] + CO2 + 3 H2O

overall reaction

an L-polyhomomethionine + [reduced NADPH-hemoprotein reductase] + O2 = an L-N-hydroxypolyhomomethionine + [oxidized NADPH-hemoprotein reductase] + H2O

(1a)