1.14.14.38: valine N-monooxygenase

This is an abbreviated version!
For detailed information about valine N-monooxygenase, go to the full flat file.

Reaction

+ 2 [reduced NADPH-hemoprotein reductase] + 2 O2 =

+ 2 [oxidized NADPH-hemoprotein reductase] +

+ 3 H2O

Synonyms

CYP79D1, CYP79D2, CYP79D3, CYP79D4, EC 1.14.13.118, N-hydroxylating cytochrome P450, valine N-monooxygenase

ECTree

1 Oxidoreductases

1.14 Acting on paired donors, with incorporation or reduction of molecular oxygen

1.14.14 With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor

1.14.14.38 valine N-monooxygenase

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Results	in table
5	AA Sequence
1	Application
4	Cloned(Commentary)
8	General Information
1	Inhibitors
4	kcat/KM [mM/s]
4	KM Value [mM]
2	Localization
2	Molecular Weight [Da]
2	Natural Substrates/ Products (Substrates)
14	Organism
4	Pathway
1	pH Optimum
2	Posttranslational Modification
1	Protein Variants
1	Purification (Commentary)
4	Reaction
12	Reference
13	Source Tissue
15	Substrates and Products (Substrate)
2	Subunits
13	Synonyms
1	Systematic Name
1	Temperature Optimum [°C]
5	Turnover Number [1/s]

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Application on EC 1.14.14.38 - valine N-monooxygenase

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agriculture

Manihot esculenta

Q9M7B7

expression of CYP79D2 from cassava in Arabidopsis thaliana results in the production of valine- and isoleucine-derived glucosinolates not normally found in this ecotype. The transgenic lines show no morphological phenotype, and the level of endogenous glucosinolates is not affected. The novel glucosinolates constitute up to 35% of the total glucosinolate content in mature rosette leaves and up to 48% in old leaves. At increased concentrations of these glucosinolates, the proportion of Val-derived glucosinolates decreases. As the isothiocyanates produced from the Val- and isoleucine-derived glucosinolates are volatile, metabolically engineered plants producing these glucosinolates have acquired novel properties with great potential for improvement of resistance to herbivorous insects and for biofumigation

710302